Effect of NAPL entrapment conditions on air sparging remediation efficiency

The effect of soil heterogeneity and the entrapment condition of NAPL source on the mass removal efficiency of air sparging coupled with soil vapour extraction (AS/SVE) was investigated using an intermediate scale two-dimensional laboratory soil tank. Four different NAPL entrapments were created by varying the height of the water table in heterogeneous soil models. Different mass removal efficiencies were achieved for different NAPL entrapment conditions, which were governed by soil heterogeneity and water table height before and during AS/SVE operation. Remobilization and redistribution of toluene and water improved the mass removal. Overall results suggested that it was difficult to achieve the complete remediation of NAPL source due to complex entrapment in heterogeneous soil system. In order to assess the potential contamination in the post-remediation stage, gas and dissolved concentrations of toluene were measured after the AS/SVE operation. The results showed that gas concentration close to remaining NAPL source zone increased rapidly and reached to steady state values, which were much smaller than the vapour pressure, whereas the aqueous phase concentrations increased continuously toward the solubility limit. (C) 2004 Elsevier B.V. All rights reserved.