Molecular Arrangements of Corannulene and Sumanene in Single-Walled Carbon Nanotubes

被引：9

作者：

Iizumi, Yoko ^{[1
,2
]}

Liu, Zheng ^{[3
]}

Suenaga, Kazu ^{[4
]}

Okada, Susumu ^{[5
,6
,7
]}

Higashibayashi, Shuhei ^{[8
]}

Sakurai, Hidehiro ^{[9
]}

Okazaki, Toshiya ^{[1
,2
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058577, Japan

[2] Natl Inst Adv Ind Sci & Technol, CNT Applicat Res Ctr, Tsukuba, Ibaraki 3058565, Japan

[3] AIST, Inorgan Funct Mat Res Inst, Nagoya, Aichi 4638560, Japan

[4] AIST, Nanomat Res Inst, Tsukuba, Ibaraki 3058565, Japan

[5] Univ Tsukuba, Inst Phys, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058577, Japan

[6] Univ Tsukuba, Ctr Computat Sci, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058577, Japan

[7] Japan Sci & Technol Agcy JST, CREST, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan

[8] Keio Univ, Fac Pharm, Minato Ku, 1-5-30 Shibakoen, Tokyo 1058512, Japan

[9] Osaka Univ, Grad Sch Engn, Dept Appl Chem, 2-1 Yamada Oka, Suita, Osaka 5650871, Japan

来源：

CHEMNANOMAT | 2018年 / 4卷 / 06期

关键词：

electron microscopy; fluorescence spectroscopy; hydrocarbons; carbon nanotubes; BAND-GAP MODIFICATION; ENCAPSULATED FULLERENES; HYDROCARBON; INVERSION; FRAGMENT; CRYSTAL;

D O I：

10.1002/cnma.201800101

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular arrangements of bowl-shaped molecules, corannulene and sumanene, in single-walled carbon nanotubes (SWCNTs) were investigated using high-resolution transmission microscopy and near-infrared photoluminescence spectroscopy. The results indicated that corannulenes are nested in SWCNTs with a random orientation, whereas sumanenes form stacked structures. The trends are consistent with the molecular orientations of corannulene and sumanene in single crystals.

引用

页码：557 / 561

页数：5

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