Photophysical characterization of a highly luminescent divalent-europium-containing azacryptate

被引:42
作者
Jenks, Tyler C. [1 ]
Bailey, Matthew D. [1 ]
Corbin, Brooke A. [1 ]
Kuda-Wedagedara, Akhila N. W. [1 ]
Martin, Philip D. [2 ]
Schlegel, H. Bernhard [1 ]
Rabuffetti, Federico A. [1 ]
Allen, Matthew J. [1 ]
机构
[1] Wayne State Univ, Dept Chem, 5101 Cass Ave, Detroit, MI 48202 USA
[2] Wayne State Univ, Dept Chem, Lumigen Instrument Ctr, 5101 Cass Ave, Detroit, MI 48202 USA
基金
美国国家科学基金会;
关键词
MAGNETIC-RESONANCE; LANTHANIDE; COMPLEXES; EU; COORDINATION; PHOSPHOR; PROBES; SENSOR; SM;
D O I
10.1039/c8cc01737a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a new luminescent Eu-II-containing complex. The complex is excited with visible light, leading to emission centered at 447 nm with a lifetime of 1.25 s. Computational studies suggest that the steric bulk of the ligand is a major factor influencing the wavelength of emission.
引用
收藏
页码:4545 / 4548
页数:4
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