Recent advances in rhodium-catalyzed cyclization reactions

被引：22
作者：
Ojima, I [1 ]
Moralee, AC [1 ]
Vassar, VC [1 ]
机构：
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
来源：
TOPICS IN CATALYSIS | 2002年 / 19卷 / 01期
关键词：
rhodium catalyst; cyclization reactions; silylformylation; carbocyclization; hydroformylation; cyclohydrocarbonylation; desymmetrization; izidine alkaloid; indolizidine; silylcyclocarbonylation (SiCCa); silylcarbocyclization (SiCaC); silylcarbobicyclization (SiCaB); silylcarbotricyclization (SiCaT); cascade reaction; Rh(acac)(CO)(2); Rh-4(CO)(12); Rh2Co2(CO)(12); carbonylative carbotricyclization; (+/-)-trachelanthamidine; (+/-)-isoretroneconol; (+)-prosopinine; (-)-deoxoprosophylline; quinolizidine; azabicyclo[XY0]alkane; amino acid; BIPHEPHOS; BINAPHOS;
D O I：
10.1023/A:1013837417361
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Mechanistic studies on silylformylation have led to the discovery of a series of new carbocyclizations involving alkynes and hydrosilanes. Cyclohydrocarbonylation processes have been devised by combining hydroformylation and cyclization. These new reactions serve as powerful methods for the rapid construction of monocyclic, bicyclic, and fused ring systems from readily obtainable starting materials.
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页码：89 / 99
页数：11
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