Steroidal saponins from the aerial parts of Tribulus alatus Del.

被引:28
作者
Temraz, Abeer
El Gindi, Omayma D.
Kadry, Hazem A.
De Tommasi, Nunziatina
Braca, Alessandra
机构
[1] Univ Pisa, Dipartimento Chim Bioorgan & Bioinform, I-56126 Pisa, Italy
[2] Al Azhar Univ, Fac Pharm, Cairo 11371, Egypt
[3] Univ Salerno, Dipartimento Sci Farmaceut, I-84084 Fisciano, SA, Italy
关键词
Tribulus alatus; Zygophyllaceae; furostane saponins; cholestane saponins; spirostane saponins;
D O I
10.1016/j.phytochem.2006.03.007
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Six steroidal glycosides (1-6) were isolated from the aerial parts of Tribulus alatus Del. (Zygophyllaceae), together with one known cholestane, one spirostane, and six flavonol glycosides. Among them, 1 and 2 possess a furostane-type aglycone. 3 and 6 a cholestane structure, and 4 and 5 a spirostane skeleton. Their Structural elucidation was accomplished by extensive spectroscopic methods including ID (H-1, C-13, C-13 DEPT, TOCSY, ROESY) and 2D NMR experiments (DQF-COSY. HSQC HMBC) as well as ESI-MS analysis. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1011 / 1018
页数:8
相关论文
共 22 条
[1]  
Achenbach H, 1996, ADV EXP MED BIOL, V404, P357
[2]   CARDIOACTIVE STEROID SAPONINS AND OTHER CONSTITUENTS FROM THE AERIAL PARTS OF TRIBULUS CISTOIDES [J].
ACHENBACH, H ;
HUBNER, H ;
BRANDT, WG ;
REITER, M .
PHYTOCHEMISTRY, 1994, 35 (06) :1527-1543
[3]  
Agrawal P.K., 1989, Carbon-13 NMR of Flavonoids
[4]   C-13 NMR SPECTRAL INVESTIGATIONS .10. C-13 NMR-SPECTROSCOPY OF STEROIDAL SAPOGENINS AND STEROIDAL SAPONINS [J].
AGRAWAL, PK ;
JAIN, DC ;
GUPTA, RK ;
THAKUR, RS .
PHYTOCHEMISTRY, 1985, 24 (11) :2479-2496
[5]  
[Anonymous], 1982, PHYTOCHEMISTRY
[6]  
Bedir E, 2002, PHARMAZIE, V57, P491
[7]   FLAVONOIDS OF FRUITS AND LEAVES OF TRIBULUS TERRESTRIS - CONSTITUTION OF TRIBULOSIDE [J].
BHUTANI, SP ;
CHIBBER, SS ;
SESHADRI, TR .
PHYTOCHEMISTRY, 1969, 8 (01) :299-+
[8]   Steroidal saponins from Tribulus terrestris [J].
Cai, LF ;
Wu, YJ ;
Zhang, JG ;
Pei, FK ;
Xu, YJ ;
Xie, SX ;
Xu, DM .
PLANTA MEDICA, 2001, 67 (02) :196-198
[9]   Furostanol saponins from Tribulus terrestris [J].
De Combarieu, E ;
Fuzzati, N ;
Lovati, M ;
Mercalli, E .
FITOTERAPIA, 2003, 74 (06) :583-591
[10]  
Ghazanfar SA, 1994, HDB ARABIAN MED PLAN