Metallopolymers cross-linked with self-assembled Ln4L4 cages

被引：15

作者：

Yan, Qian-Qian ^{[1
]}

Zhou, Li-Peng ^{[1
]}

Zhou, Hai-Yue ^{[1
,2
]}

Wang, Zhuo ^{[1
,3
]}

Cai, Li-Xuan ^{[1
]}

Guo, Xiao-Qing ^{[1
,3
]}

Sun, Xiao-Qi ^{[1
,2
]}

Sun, Qing-Fu ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Haixi Inst, Xiamen Inst Rare Earth Mat, Xiamen 361021, Fujian, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 21期

关键词：

ORGANOMETALLIC CAGES; HOST-GUEST; LANTHANIDE; METAL; WATER; CONSTRUCTION; COMPLEXES; CATALYSIS; STRATEGY;

D O I：

10.1039/c8dt05015e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, we fabricated a hybrid PDVB-Ln(4)L(4) metallopolymer using a vinyl functionalized lanthanide-organic tetrahedral cage as the cross-linking agent. Such a covalent embedding strategy not only tunes the morphology and porosity of the metallopolymer, but also improves the luminescence property of the lanthanide organic polyhedron. Potential application in lanthanide separation has also been demonstrated. This study provides a potential strategy for the immobilization of multinuclear lanthanide-organic edifices toward heterogeneous application.

引用

页码：7080 / 7084

页数：5

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