Synthesis, structure, and thermal behavior of polymeric zinc(ii) pivalate

被引：20
|
作者：
Fomina, I. G. [1 ]
Chernyshev, V. V. [2 ,3 ]
Velikodnyi, Yu. A. [2 ]
Bykov, M. A. [2 ]
Malkerova, I. P. [1 ]
Alikhanyan, A. S. [1 ]
Zavorotnyi, Yu. S. [4 ]
Dobrokhotova, Zh. V. [1 ]
Eremenko, I. L. [1 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, 31 Leninsky Prosp, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[3] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia
[4] Moscow MV Lomonosov State Univ, DV Skobeltsyn Inst Nucl Phys, Moscow 119992, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
zinc pivalate; coordination polymer; synthesis; X-ray powder diffraction; thermal behavior; MAGNETIC-PROPERTIES; POWDER; RELIABILITY; COMPLEXES; CRITERION; COBALT; CO;
D O I：
10.1007/s11172-013-0057-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of zinc(ii) acetate hydrate with pivalic acid (HOOCBut- = HPiv) in air at 100 A degrees C afforded the new 1D coordination polymer {Zn(Piv)(2)} (n) (1), in which the metal atoms are in a tetrahedral ligand environment. The thermal behavior of the resulting compound and the sublimation and vaporization processes in the temperature range of 430-550 K were studied by differential scanning calorimetry and thermogravimetric analysis. The structure of compound 1 was determined by X-ray powder diffraction.
引用
收藏
页码：427 / 434
页数：8
相关论文
共 50 条
  • [41] Synthesis and structure of a novel bridged binuclear zinc(II) complex
    Liu, XL
    Zhao, R
    Liu, XH
    Yue, JJ
    Chen, K
    Miao, FM
    ACTA CHIMICA SINICA, 2003, 61 (04) : 578 - 583
  • [42] Synthesis, characterization and crystal structure of a glycylglycinate chelate of zinc(II)
    Case, Derek R.
    Brennessel, William W.
    Zubieta, Jon
    Doyle, Robert P.
    RESULTS IN CHEMISTRY, 2022, 4
  • [43] Synthesis, Crystal Structure, and Cytotoxiciy In Vitro of a Zinc(II) Complex
    Miao, Jian-Ying
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (11) : 1683 - 1686
  • [44] Synthesis, Structure and Luminescent Property of a New Zinc(II) Complex
    Zhai Ji-Quan
    Zhang Yu
    Cheng Jian-Kai
    Yang Jin-Xia
    Zhang Xin
    Qin Ye-Yan
    Yao Yuan-Gen
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (10) : 1513 - 1518
  • [45] Polymeric haloplumbates(II) templated by ethoxycarbonylmethyl viologen: Structure and enchanced thermochromism behavior
    Chen, Bao-Guo
    INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (08) : 1220 - 1225
  • [46] Synthesis and Characterization of Zinc(II) Oxide Nanoparticles by Thermal Decomposition of Two Zinc(II) Nitrite Coordination Polymer Precursors
    Aghabeygi, Shokufeh
    Bigdeli, Fahime
    Morsali, Ali
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2012, 22 (02) : 526 - 529
  • [47] Synthesis and Characterization of Zinc(II) Oxide Nanoparticles by Thermal Decomposition of Two Zinc(II) Nitrite Coordination Polymer Precursors
    Shokufeh Aghabeygi
    Fahime Bigdeli
    Ali Morsali
    Journal of Inorganic and Organometallic Polymers and Materials, 2012, 22 : 526 - 529
  • [48] Synthesis, crystal structure and fluorescence of a 1-D polymeric zinc(II) complex with pyrazine-2-carboxylate as a bridging ligand
    Li, JM
    Shi, JM
    Wu, CJ
    Xu, W
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (10) : 869 - 875
  • [49] Synthesis, Crystal Structure and Thermal Behavior of Methyleneaminonitroguanidine (MANG)
    Yang H.
    Feng Z.C.
    Guan X.G.
    Xu K.Z.
    Song J.R.
    Zhao F.Q.
    Hanneng Cailiao/Chinese Journal of Energetic Materials, 2019, 27 (02): : 125 - 130
  • [50] Synthesis, Crystal Structure and Thermal Behavior of Cs(DNDZ)
    Xu Kang-Zhen
    Zuo Xian-Gang
    Zhang Hang
    Wang Min
    Song Ji-Rong
    Zhao Feng-Qi
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (11) : 2257 - 2262
12345