Synthesis, structure, and thermal behavior of polymeric zinc(ii) pivalate

被引：20
|
作者：
Fomina, I. G. [1 ]
Chernyshev, V. V. [2 ,3 ]
Velikodnyi, Yu. A. [2 ]
Bykov, M. A. [2 ]
Malkerova, I. P. [1 ]
Alikhanyan, A. S. [1 ]
Zavorotnyi, Yu. S. [4 ]
Dobrokhotova, Zh. V. [1 ]
Eremenko, I. L. [1 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, 31 Leninsky Prosp, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[3] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia
[4] Moscow MV Lomonosov State Univ, DV Skobeltsyn Inst Nucl Phys, Moscow 119992, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
zinc pivalate; coordination polymer; synthesis; X-ray powder diffraction; thermal behavior; MAGNETIC-PROPERTIES; POWDER; RELIABILITY; COMPLEXES; CRITERION; COBALT; CO;
D O I：
10.1007/s11172-013-0057-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of zinc(ii) acetate hydrate with pivalic acid (HOOCBut- = HPiv) in air at 100 A degrees C afforded the new 1D coordination polymer {Zn(Piv)(2)} (n) (1), in which the metal atoms are in a tetrahedral ligand environment. The thermal behavior of the resulting compound and the sublimation and vaporization processes in the temperature range of 430-550 K were studied by differential scanning calorimetry and thermogravimetric analysis. The structure of compound 1 was determined by X-ray powder diffraction.
引用
收藏
页码：427 / 434
页数：8
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