Synthesis of MCM-48 by a phase transformation process

被引：135
作者：
Gallis, KW [1 ]
Landry, CC [1 ]
机构：
[1] UNIV VERMONT, DEPT CHEM, BURLINGTON, VT 05405 USA
来源：
CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 10期
关键词：
D O I：
10.1021/cm970482m
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ordered mesoporous silicate MCM-48 has been produced from MCM-41 by a phase transformation method, which involves heating the silicate samples while they are still incompletely polymerized. Ethanol, produced by hydrolysis of the silicate source TEOS, plays a crucial role in the transformation process. In this report, we examine samples produced using various combinations of stirring and heating times with XRD and Si-29 MAS NMR and draw conclusions regarding the reasons for the transformation.
引用
收藏
页码：2035 / +
页数：1
相关论文
共 22 条
  • [1] MOLECULAR OR SUPRAMOLECULAR TEMPLATING - DEFINING THE ROLE OF SURFACTANT CHEMISTRY IN THE FORMATION OF MICROPOROUS AND MESOPOROUS MOLECULAR-SIEVES
    BECK, JS
    VARTULI, JC
    KENNEDY, GJ
    KRESGE, CT
    ROTH, WJ
    SCHRAMM, SE
    [J]. CHEMISTRY OF MATERIALS, 1994, 6 (10) : 1816 - 1821
  • [2] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
    BECK, JS
    VARTULI, JC
    ROTH, WJ
    LEONOWICZ, ME
    KRESGE, CT
    SCHMITT, KD
    CHU, CTW
    OLSON, DH
    SHEPPARD, EW
    MCCULLEN, SB
    HIGGINS, JB
    SCHLENKER, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
  • [3] STUDIES ON MESOPOROUS MATERIALS .2. SYNTHESIS MECHANISM OF MCM-41
    CHEN, CY
    BURKETT, SL
    LI, HX
    DAVIS, ME
    [J]. MICROPOROUS MATERIALS, 1993, 2 (01): : 27 - 34
  • [4] STUDIES ON ORDERED MESOPOROUS MATERIALS .3. COMPARISON OF MCM-41 TO MESOPOROUS MATERIALS DERIVED FROM KANEMITE
    CHEN, CY
    XIAO, SQ
    DAVIS, ME
    [J]. MICROPOROUS MATERIALS, 1995, 4 (01): : 1 - 20
  • [5] THE ROLE OF SURFACTANT MICELLES IN THE SYNTHESIS OF THE MESOPOROUS MOLECULAR-SIEVE MCM-41
    CHENG, CF
    LUAN, ZH
    KLINOWSKI, J
    [J]. LANGMUIR, 1995, 11 (07) : 2815 - 2819
  • [6] Further improvements in the long-range order of MCM-41 materials
    Edler, KJ
    White, JW
    [J]. CHEMISTRY OF MATERIALS, 1997, 9 (05) : 1226 - 1233
  • [7] Engelhardt G., 1987, HIGH RESOLUTION SOLI
  • [8] Alkaline lyotropic silicate-surfactant liquid crystals
    Firouzi, A
    Atef, F
    Oertli, AG
    Stucky, GD
    Chmelka, BF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (15) : 3596 - 3610
  • [9] COOPERATIVE ORGANIZATION OF INORGANIC-SURFACTANT AND BIOMIMETIC ASSEMBLIES
    FIROUZI, A
    KUMAR, D
    BULL, LM
    BESIER, T
    SIEGER, P
    HUO, Q
    WALKER, SA
    ZASADZINSKI, JA
    GLINKA, C
    NICOL, J
    MARGOLESE, D
    STUCKY, GD
    CHMELKA, BF
    [J]. SCIENCE, 1995, 267 (5201) : 1138 - 1143
  • [10] GENERALIZED SYNTHESIS OF PERIODIC SURFACTANT INORGANIC COMPOSITE-MATERIALS
    HUO, QS
    MARGOLESE, DI
    CIESLA, U
    FENG, PY
    GIER, TE
    SIEGER, P
    LEON, R
    PETROFF, PM
    SCHUTH, F
    STUCKY, GD
    [J]. NATURE, 1994, 368 (6469) : 317 - 321
123