Catalytic oxidation of chlorinated hydrocarbons in two-component mixtures with selected VOCs

被引：28

作者：

Musialik-Piotrowska, A ^{[1
]}

Mendyka, B ^{[1
]}

机构：

[1] Wroclaw Univ Technol, Inst Environm Protect Engn, PL-50370 Wroclaw, Poland

来源：

CATALYSIS TODAY | 2004年 / 90卷 / 1-2期

关键词：

air pollution control; chlorobenzene; 1,2-dichloroethane;

D O I：

10.1016/j.cattod.2004.04.019

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The catalytic oxidation of chlorobenzene (ChB) and 1,2-dichloroethane (DCE) oxidized alone and in two-component mixtures with selected non-chlorinated volatile organic compounds (VOCs) such as toluene, n-hexane, acetone ethanol, ethyl acetate, was investigated. The tests were carried out over Pt-based catalyst on a monolithic metallic support. Only both hydrocarbons and ethanol enhanced ChB oxidation. DCE conversion was inhibited in the presence of each non-chlorinated admixture. Both chlorinated compounds lowered the catalytic reactivity of non-chlorinated VOCs and increased the concentration of incomplete oxidation products, first of all acetaldehyde. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：139 / 144

页数：6

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