Ag(I)/(C2H5)4NCl Cooperation Catalysis for Fixing CO2 or Its Derivatives into β-Oxopropylcarbamates

被引：12

作者：

Zhao, Qing-Ning ^{[1
]}

Song, Qing-Wen ^{[2
]}

Liu, Ping ^{[2
]}

Zhang, Kan ^{[2
]}

Hao, Jian ^{[1
]}

机构：

[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China

[2] Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Shanxi, Peoples R China

来源：

CHEMISTRYSELECT | 2018年 / 3卷 / 24期

基金：

中国国家自然科学基金;

关键词：

Carbon dioxide fixation; Homogeneous catalysis; beta-Oxopropylcarbamates; Silver catalysis; Synthetic method; CARBON-DIOXIDE INCORPORATION; ECO-FRIENDLY PROCESS; PROPARGYLIC ALCOHOLS; CYCLIC CARBONATES; EFFICIENT; TRANSFORMATION; COPPER; ACTIVATION; CONVERSION; MECHANISM;

D O I：

10.1002/slct.201801422

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It remains a great challenge to convert CO2 into high value-added products under ambient pressure. Herein, an efficient dual-component catalytic system, i.e., Ag(I)/(C2H5)(4)NCl was developed for the synthesis of various beta-oxopropylcarbamates via one-pot three-component coupling of CO2, secondary amines and propargylic alcohols under atmospheric pressure. Besides, the strategy avoided the use of any additional ligand and basic species, and excellent selectivity was achieved with a yield of up to 98%. Additionally, C-13(carbonyl)-labeled and control experiments were carefully performed to demonstrate the mechanism. Notably, this new method was also applied efficiently in quantitative chemical fixation of CO2, i.e., the two-component reaction of propargylic alcohols and ammonium carbamates.

引用

页码：6897 / 6901

页数：5

共 50 条

[21] Effects of electrolytes on the electrochemical reduction of CO2 to C2H4: a mechanistic point of view
Ma, Xifei
Xing, Lu
Liu, Kaisi
Liu, Lei
CATALYSIS SCIENCE & TECHNOLOGY, 2023, 13 (03) : 788 - 801
[22] Triplet-quintet spin-crossover efficiency in fl-hydrogen transfer between Fe (C2H5)+ and HFe(C2H4)+
Murakami, Tatsuhiro
Takayanagi, Toshiyuki
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2022, 1217
[23] F-modified Cu/electrolyte interface boosts CO2 electroreduction into C2H4 and C2H5OH products via an alternative C-C coupling mechanism
Ou, Lihui
MOLECULAR CATALYSIS, 2025, 570
[24] Copper(II) and Nickel(II) Alkylxanthate Complexes (R = C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11): EPR and Solid-State 13C CP/MAS NMR Studies
A. V. Ivanov
O. A. Bredyuk
O. N. Antzutkin
W. Forsling
Russian Journal of Coordination Chemistry, 2004, 30 : 480 - 485
[25] Achieving highly selective electrochemical CO2 reduction to C2H4 on Cu nanosheets
Xie, Huan
Xie, Ruikuan
Zhang, Zhiyuan
Pang, Yongyu
Luo, Yuting
Li, Jiong
Liu, Bilu
Titirici, Maria -Magdalena
Chai, Guoliang
JOURNAL OF ENERGY CHEMISTRY, 2023, 79 : 312 - 320
[26] Heterobimetallic praseodymium-nickel active sites with Pr-N4C2 4 C 2 and Ni-N4 4 moieties enabling synergistic catalysis of CO2 2 electroreduction
Zhang, Heng
Cao, Yajie
Sun, Min
Liu, Yang
Wang, Yan
Li, Haorun
Zhang, Riguang
Gu, Xiaojun
Zeng, Shanghong
CHEMICAL ENGINEERING JOURNAL, 2024, 490
[27] Efficient Electrochemical Production of Syngas from CO2 and H2O by using a Nanostructured Ag/g-C3N4 Catalyst
Sastre, Francesc
Munoz-Batista, Mario J.
Kubacka, Anna
Fernandez-Garcia, Marcos
Smith, Wilson A.
Kapteijn, Freek
Makkee, Michiel
Gascon, Jorge
CHEMELECTROCHEM, 2016, 3 (09): : 1497 - 1502
[28] Promoted selectivity of photocatalytic CO2 reduction to C2H4 via hybrid CuxCoSy possessing dual unsaturated sites
Nie, Yu
Li, Yanfang
An, Chao
Tan, Xin
Hu, Zhuofeng
Ye, Jinhua
Yu, Tao
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2024, 345
[29] Catalyst-free hierarchical reduction of CO2 with BH3N(C2H5)3 for selective N-methylation and N-formylation of amines
Zou, Qizhuang
Yi, Yun
Zhao, Tianxiang
Liu, Fei
Kang, Chao
Hu, Xingbang
JOURNAL OF CO2 UTILIZATION, 2021, 50
[30] Homogeneous Catalysis for the Conversion of CO2, CO, CH3OH, and CH4 to C2+Chemicals via C-C Bond Formation
Fors, Stella A.
Malapit, Christian A.
ACS CATALYSIS, 2023, 13 (07): : 4231 - 4249

← 1 2 3 4 5 →