Validated Reduction and Accelerated Numerical Computation of a Model for the Proton Exchange Membrane Fuel Cell

被引:19
作者
Ly, H. [1 ]
Birgersson, E. [1 ]
Vynnycky, M. [2 ]
Sasmito, A. P. [3 ]
机构
[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117576, Singapore
[2] Univ Limerick, Dept Math & Stat, Math Applicat Consortium Sci & Ind, Limerick, Ireland
[3] Natl Univ Singapore, Dept Mech Engn, Singapore 117575, Singapore
基金
爱尔兰科学基金会;
关键词
GAS-DIFFUSION LAYERS; NONISOTHERMAL MODEL; MATHEMATICAL-MODEL; CATALYST LAYERS; 2-PHASE MODEL; MASS-TRANSFER; METAL FOAM; FLOW-FIELD; WATER; TRANSPORT;
D O I
10.1149/1.3160571
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Amongst the severest drawbacks of many models for the proton exchange membrane fuel cell (PEMFC) are excessive memory requirements and computing time; consequently, using these for stack modeling is impractical. While reduced models alleviate these difficulties to some extent, most of the available reduced models do not preserve geometrical resolution. In this paper, we present a reduced model for a PEMFC that both reduces computational requirements and preserves geometrical resolution. The model is for a PEMFC equipped with porous flow fields and takes into account conservation of mass, momentum, species, energy, and charge. The results of the reduced model are then verified against those of the full model and validated against global polarization curves and local current-density distributions for three different experimental fuel cells; good agreement is obtained. In computational terms, the Solution of the reduced model is found to require between 2 and 3 orders of magnitude less random access memory and execution time than that of the full model; furthermore, it scales well when run on up to four processors. Finally, we discuss the suitability of our reduced model for extension to a PEMFC stack model comprising tens or hundreds of single cells. (C) 2009 The Electrochemical Society. [DOI: 10.1149/1.3160571] All rights reserved.
引用
收藏
页码:B1156 / B1168
页数:13
相关论文
共 67 条
  • [11] Reduced dimensional computational models of polymer electrolyte membrane fuel cell stacks
    Chang, Paul
    Kim, Gwang-Soo
    Promislow, Keith
    Wetton, Brian
    [J]. JOURNAL OF COMPUTATIONAL PHYSICS, 2007, 223 (02) : 797 - 821
  • [12] Mathematical model of a PEMFC using a PBI membrane
    Cheddie, D
    Munroe, N
    [J]. ENERGY CONVERSION AND MANAGEMENT, 2006, 47 (11-12) : 1490 - 1504
  • [13] Three dimensional modeling of high temperature PEM fuel cells
    Cheddie, Denver F.
    Munroe, Norman D. H.
    [J]. JOURNAL OF POWER SOURCES, 2006, 160 (01) : 215 - 223
  • [14] *COMSOL, COMSOL MULT 3 5A
  • [15] Transport phenomena in polymer electrolyte membranes - I. Modeling framework
    Fimrite, J
    Struchtrup, H
    Djilali, N
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (09) : A1804 - A1814
  • [16] In-plane effects in large-scale PEMFCs -: Model formulation and validation
    Freunberger, SA
    Santis, M
    Schneider, IA
    Wokaun, A
    Büchi, FN
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (02) : A396 - A405
  • [17] Capillary pressure and hydrophilic porosity in gas diffusion layers for polymer electrolyte fuel cells
    Gostick, Jeffrey T.
    Fowler, Michael W.
    Ioannidis, Marios A.
    Pritzker, Mark D.
    Volfkovich, Y. M.
    Sakars, A.
    [J]. JOURNAL OF POWER SOURCES, 2006, 156 (02) : 375 - 387
  • [18] Two-dimensional model for proton exchange membrane fuel cells
    Gurau, V
    Liu, HT
    Kakac, S
    [J]. AICHE JOURNAL, 1998, 44 (11) : 2410 - 2422
  • [19] An analytical solution of a half-cell model for PEM fuel cells
    Gurau, V
    Barbir, F
    Liu, HT
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (07) : 2468 - 2477
  • [20] Characterization of gas diffusion layers for PEMFC
    Han, M.
    Xu, J. H.
    Chan, S. H.
    Jiang, S. P.
    [J]. ELECTROCHIMICA ACTA, 2008, 53 (16) : 5361 - 5367