Chalcogen and Hydrogen Bonds at the Periphery of Arylhydrazone Metal Complexes

被引：16

作者：

Gurbanov, Atash, V ^{[1
,3
]}

Kuznetsov, Maxim L. ^{[1
]}

Resnati, Giuseppe ^{[2
]}

Mahmudov, Kamran T. ^{[1
,3
]}

Pombeiro, Armando J. L. ^{[1
,4
]}

机构：

[1] Univ Lisbon, Ctr Quim Estrutural, Inst Mol Sci, Inst Super Tecn, P-1049001 Lisbon, Portugal

[2] Politecn Milan, Lab Nanostruct Fluorinated Mat NFMLab, Dept Chem Mat & Chem Engn Giulio Natta, I-20131 Milan, Italy

[3] Baku State Univ, Dept Chem, Baku 1148, Azerbaijan

[4] Peoples Friendship Univ Russia RUDN Univ, Res Inst Chem, Moscow 117198, Russia

来源：

CRYSTAL GROWTH & DESIGN | 2022年 / 22卷 / 06期

关键词：

NONCOVALENT INTERACTIONS; SOLID-STATE; COORDINATION; DESIGN; CHEMISTRY; INSIGHTS; CRYSTAL; HALOGEN;

D O I：

10.1021/acs.cgd.2c00322

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ligands comprising an intramolecular resonance-assisted hydrogen bond (RAHB) and an intramolecular resonance-assisted chalcogen bond (RAChB) have been used to form Cu(II), Ag(I), and Cd(II) metal complexes. Both interactions undergo major changes on ligand binding to the metal even though metal-ligand binding does not directly involve either interactions. In fact, the RAChB synthon can act as an intermolecular H-bond donor or acceptor, is involved in intramolecular coordination-coupled proton transfer, or exhibits an ionic pattern.

引用

页码：3932 / 3940

页数：9

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