Optical and Electrical Properties of CuO Thin Films by Spray Pyrolysis Method

被引：3

作者：

Kuryshchuk, S., I ^{[1
]}

Orletskii, I. G. ^{[1
]}

Shyrokov, O., V ^{[2
]}

Myroniuk, D., V ^{[2
]}

Solovan, M. M. ^{[1
]}

机构：

[1] Yuriy Fedkovych Chernivtsi Natl Univ, Dept Elect & Power Engn, 2 Kotsubynsky St, UA-58002 Chernovtsy, Ukraine

[2] Natl Acad Sci Ukraine, Inst Problems Mat Sci, 3 Krhyzhanovsky St, UA-03142 Kiev, Ukraine

来源：

ACTA PHYSICA POLONICA A | 2022年 / 142卷 / 05期

关键词：

CuO; spray pyrolysis; optical properties; thin films; NANOSTRUCTURES; TEMPERATURE;

D O I：

10.12693/APhysPolA.142.625

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Thin films (300 nm thick) of CuO of p-type conductivity were precipitated using the spray pyrolysis method from 0.2 M of aqueous CuCl2 center dot 2H(2)O salt solution on preheated (up to 350 degrees C) glass and sitall substrates. The structure and electrical and optical properties of the films are analyzed. The grain size of CuO thin films (24 nm) was calculated using the XRD analysis. The activation energy equals E-a = 0.27 eV, which may indicate that the conduction is due to the transition of charge carriers from the valence band to the working acceptor level. From the spectral dependence (alpha h nu)(2) = f(h nu) of CuO thin films, the band gap width E-g = 1.46 eV was determined.

引用

页码：625 / 628

页数：4

共 27 条

[1] Dye sensitized solar cells using catalytically active CuO-ZnO nanocomposite synthesized by single step method [J].

Abraham, Nelsa ;

Rufus, Alex ;

Unni, C. ;

Philip, Daizy .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2018, 200 :116-126

[2] CuO based solar cell with V2O5 BSF layer: Theoretical validation of experimental data [J].

Ahmmed, Shamim ;

Aktar, Asma ;

Tabassum, Samia ;

Rahman, Md Hafijur ;

Rahman, Md Ferdous ;

Ismail, Abu Bakar Md .

SUPERLATTICES AND MICROSTRUCTURES, 2021, 151

[3] The structure and properties of copper oxide and copper aluminium oxide coatings prepared by pulsed magnetron sputtering of powder targets [J].

Alkoy, EM ;

Kelly, PJ .

VACUUM, 2005, 79 (3-4) :221-230

[4] Optical, structural and phase transition properties of Cu2O, CuO and Cu2O/CuO: Their photoelectrochemical sensor applications [J].

Balik, Meral ;

Bulut, Veysel ;

Erdogan, Ibrahim Y. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (34) :18744-18755

[5]

Choi S.H., 2017, J RES ENV EARTH SCI, V3, P47

[6] Structural and optical transmittance analysis of CuO thin films deposited by the spray pyrolysis method [J].

Daira, R. ;

Kabir, A. ;

Boudjema, B. ;

Sedrati, C. .

SOLID STATE SCIENCES, 2020, 104 (104)

[7]

Datta P, 2021, J OPTOELECTRON ADV M, V23, P35

[8] Controlling carbon monoxide emissions from automobile vehicle exhaust using copper oxide catalysts in a catalytic converter [J].

Dey, S. ;

Dhal, G. Chandra .

MATERIALS TODAY CHEMISTRY, 2020, 17

[9] Morphology and structure of CuO nanostructures grown via thermal oxidation on glass, silicon, and quartz at different oxidation temperatures [J].

Faisal, Abdulqader D. ;

Khalef, Wafaa Khalid .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (24) :18903-18912

[10] ELECTRONIC-STRUCTURE OF CU2O AND CUO [J].

GHIJSEN, J ;

TJENG, LH ;

VANELP, J ;

ESKES, H ;

WESTERINK, J ;

SAWATZKY, GA ;

CZYZYK, MT .

PHYSICAL REVIEW B, 1988, 38 (16) :11322-11330

← 1 2 3 →