Manganese organometallic compounds in homogeneous catalysis: Past, present, and prospects

被引：256

作者：

Valyaev, Dmitry A. ^{[1
,2
]}

Lavigne, Guy ^{[1
,2
]}

Lugan, Noel ^{[1
,2
]}

机构：

[1] CNRS, Lab Chim Coordinat, UPR 8241, F-31077 Toulouse 4, France

[2] Univ Toulouse, UPS, INPT, F-31077 Toulouse 4, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2016年 / 308卷

关键词：

Organometallic manganese complexes; Cross-coupling; C-H activation; Hydrosilylation; CO2; reduction; Electrochemical hydrogen production; CROSS-COUPLING REACTION; CARBON SINGLE BOND; ELECTROCATALYTIC CO2 REDUCTION; ALLYL 2-IODOPHENYL ETHER; MN-III CATALYST; C-H ACTIVATION; GRIGNARD-REAGENTS; 1,3-DICARBONYL COMPOUNDS; BINUCLEAR ELIMINATION; TERMINAL ALKYNES;

D O I：

10.1016/j.ccr.2015.06.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of first row transition metal complexes is one of the mainstreams in modern homogeneous catalysis. The case of manganese is peculiar in that catalytic applications of its coordination compounds featuring nitrogen- and oxygen-based ligands are well established, whereas those of its organometallic complexes exhibiting Mn-C and/or Mn-H bonds are still underdeveloped and have only recently focused substantial attention. The aim of the present report is to provide for the first time a comprehensive overview of this rapidly emerging area and to outline some prospects. (C) 2015 Published by Elsevier B.V.

引用

页码：191 / 235

页数：45

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