共 34 条
Tungsten Oxide and Polyaniline Composite Fabricated by Surfactant-Templated Electrodeposition and Its Use in Supercapacitors
被引:26
作者:

Zou, Benxue
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机构:
Liaodong Univ, Dept Chem Engn, Dandong 118003, Peoples R China Liaodong Univ, Dept Chem Engn, Dandong 118003, Peoples R China

Gong, Shengchen
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机构:
Liaodong Univ, Dept Chem Engn, Dandong 118003, Peoples R China Liaodong Univ, Dept Chem Engn, Dandong 118003, Peoples R China

Wang, Yan
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机构:
Liaodong Univ, Dept Chem Engn, Dandong 118003, Peoples R China Liaodong Univ, Dept Chem Engn, Dandong 118003, Peoples R China

Liu, Xiaoxia
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机构:
Northeastern Univ, Dept Chem, Shenyang, Peoples R China Liaodong Univ, Dept Chem Engn, Dandong 118003, Peoples R China
机构:
[1] Liaodong Univ, Dept Chem Engn, Dandong 118003, Peoples R China
[2] Northeastern Univ, Dept Chem, Shenyang, Peoples R China
关键词:
ELECTROCHEMICAL SYNTHESIS;
FILMS;
NANOCOMPOSITE;
PERFORMANCE;
NANOFIBERS;
TRIOXIDE;
D O I:
10.1155/2014/813120
中图分类号:
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Composite nanostructures of tungsten oxide and polyaniline (PANI) were fabricated on carbon electrode by electrocodeposition using sodium dodecylbenzene sulfonate (SDBS) as the template. The morphology of the composite can be controlled by changing SDBS surfactant and aniline monomer concentrations in solution. With increasing concentration of aniline in surfactant solution, the morphological change from nanoparticles to nanofibers was observed. The nanostructured WO3/PANI composite exhibited enhanced capacitive charge storage with the specific capacitance of 201 F g(-1) at 1.28 mA cm(-2) in large potential window of -0.5 similar to 0.65V versus SCE compared to the bulk composite film. The capacitance retained about 78% when the sweeping potential rate increased from 10 to 150mV/s.
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