Dopant-Free Planar n-i-p Perovskite Solar Cells with Steady-State Efficiencies Exceeding 18%

被引：71

作者：

Habisreutinger, Severin N. ^{[1
]}

Wenger, Bernard ^{[1
]}

Snaith, Henry J. ^{[1
]}

Nicholas, Robin J. ^{[1
]}

机构：

[1] Univ Oxford, Clarendon Lab, Dept Phys, Parks Rd, Oxford OX1 3PU, England

来源：

ACS ENERGY LETTERS | 2017年 / 2卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

HOLE-TRANSPORT MATERIALS; HIGHLY EFFICIENT; ANOMALOUS HYSTERESIS; LITHIUM-SALTS; PERFORMANCE; EXTRACTION; ABSORBER; MOBILITY; LAYER;

D O I：

10.1021/acsenergylett.7b00028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this Letter, we demonstrate a planar n-i-p perovskite solar cell design with a steady-state efficiency of up to 18.8% in the absence of any electronic dopants. In the device stack, solution-processed SnO2 is used as an electron-accepting n-type layer. The absorber layer is a perovskite with both mixed organic A-site cations and mixed halides (FA(0.83)MA(0.17)Pb(I0.83Br0.17)(3)). The hole-transporting p-type layer is a double-layer structure of polymer-wrapped single-walled carbon nanotubes and undoped spiro-OMeTAD. We show that this approach can deliver steady-state efficiencies as high as and even higher than those of traditionally doped spiro-OMeTAD, providing a pathway for dopant-free perovskite solar cells crucial for long-term stability. [GRAPHICS]

引用

页码：622 / 628

页数：7

共 42 条

[1]

Abate A, 2013, PHYS CHEM CHEM PHYS, V15, P2572, DOI [10.1039/c2cp44397J, 10.1039/c2cp44397j]

[2] Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide [J].

Anaraki, Elham Halvani ;

Kermanpur, Ahmad ;

Steier, Ludmilla ;

Domanski, Konrad ;

Matsui, Taisuke ;

Tress, Wolfgang ;

Saliba, Michael ;

Abate, Antonio ;

Gratzel, Michael ;

Hagfeldt, Anders ;

Correa-Baena, Juan-Pablo .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (10) :3128-3134

[3] Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].

Bach, U ;

Lupo, D ;

Comte, P ;

Moser, JE ;

Weissörtel, F ;

Salbeck, J ;

Spreitzer, H ;

Grätzel, M .

NATURE, 1998, 395 (6702) :583-585

[4] Highly efficient planar perovskite solar cells through band alignment engineering [J].

Baena, Juan Pablo Correa ;

Steier, Ludmilla ;

Tress, Wolfgang ;

Saliba, Michael ;

Neutzner, Stefanie ;

Matsui, Taisuke ;

Giordano, Fabrizio ;

Jacobsson, T. Jesper ;

Kandada, Ajay Ram Srimath ;

Zakeeruddin, Shaik M. ;

Petrozza, Annamaria ;

Abate, Antonio ;

Nazeeruddin, Mohammad Khaja ;

Graetzel, Michael ;

Hagfeldt, Anders .

ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (10) :2928-2934

[5] Hole-Transport Materials for Perovskite Solar Cells [J].

Calio, Laura ;

Kazim, Samrana ;

Graetzel, Michael ;

Ahmad, Shahzada .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (47) :14522-14545

[6] Ionic transport in hybrid lead iodide perovskite solar cells [J].

Eames, Christopher ;

Frost, Jarvist M. ;

Barnes, Piers R. F. ;

O'Regan, Brian C. ;

Walsh, Aron ;

Islam, M. Saiful .

NATURE COMMUNICATIONS, 2015, 6

[7] Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells [J].

Eperon, Giles E. ;

Burlakov, Victor M. ;

Docampo, Pablo ;

Goriely, Alain ;

Snaith, Henry J. .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (01) :151-157

[8] Investigating the Role of 4-Tert Butylpyridine in Perovskite Solar Cells [J].

Habisreutinger, Severin N. ;

Noel, Nakita K. ;

Snaith, Henry J. ;

Nicholas, Robin J. .

ADVANCED ENERGY MATERIALS, 2017, 7 (01)

[9] Research Update: Strategies for improving the stability of perovskite solar cells [J].

Habisreutinger, Severin N. ;

McMeekin, David P. ;

Snaith, Henry J. ;

Nicholas, Robin J. .

APL MATERIALS, 2016, 4 (09)

[10] Enhanced Hole Extraction in Perovskite Solar Cells Through Carbon Nanotubes [J].

Habisreutinger, Severin N. ;

Leijtens, Tomas ;

Eperon, Giles E. ;

Stranks, Samuel D. ;

Nicholas, Robin J. ;

Snaith, Henry J. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (23) :4207-4212

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