Reactivity of a 1-azavinylidene ligand with diphenylacetylene on a ruthenium carbonyl cluster. A remarkable alkyne insertion into a metal-nitrogen bond

被引：19

作者：

Cabeza, JA ^{[1
]}

delRio, I ^{[1
]}

Franco, RJ ^{[1
]}

Grepioni, F ^{[1
]}

Riera, V ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 13期

关键词：

D O I：

10.1021/om970259z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The insertion of diphenylcetylene into a ruthelzium-nitrogen bond is a hey step in the preparation of the binuclear derivative 2. This is the first example of insertion of a little electrophilic alkyne into a metal-nitrogen bond.

引用

页码：2763 / 2764

页数：2

共 20 条

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