The Tris(trifluoromethyl)methyl Phosphonium Ion, P(CF3)3CH3+, Preparation and Structure

被引：6

作者：

Shyshkov, Oleg ^{[1
]}

Dieckbreder, Uwe ^{[1
]}

Drews, Thomas ^{[2
]}

Kolomeitsev, Alexander ^{[1
]}

Roeschenthaler, Gerd-Volker ^{[1
]}

Seppelt, Konrad ^{[2
]}

机构：

[1] Univ Bremen, Inst Inorgan & Phys Chem, D-28334 Bremen, Germany

[2] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

ELECTRON-DIFFRACTION; MOLECULAR-STRUCTURE; ORGANOMETALLIC COMPOUNDS; RADICAL EXCHANGE; CHEMISTRY; STEREOCHEMISTRY; REPLACEMENT; METHYL;

D O I：

10.1021/ic900414q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

P(CF3)(3) cannot be protonated, not even by HF/SbF5. However, it can be methylated to P(CF3)(3)CH3+.

引用

页码：6083 / 6085

页数：3

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