The Tris(trifluoromethyl)methyl Phosphonium Ion, P(CF3)3CH3+, Preparation and Structure

被引：6

作者：

Shyshkov, Oleg ^{[1
]}

Dieckbreder, Uwe ^{[1
]}

Drews, Thomas ^{[2
]}

Kolomeitsev, Alexander ^{[1
]}

Roeschenthaler, Gerd-Volker ^{[1
]}

Seppelt, Konrad ^{[2
]}

机构：

[1] Univ Bremen, Inst Inorgan & Phys Chem, D-28334 Bremen, Germany

[2] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

ELECTRON-DIFFRACTION; MOLECULAR-STRUCTURE; ORGANOMETALLIC COMPOUNDS; RADICAL EXCHANGE; CHEMISTRY; STEREOCHEMISTRY; REPLACEMENT; METHYL;

D O I：

10.1021/ic900414q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

P(CF3)(3) cannot be protonated, not even by HF/SbF5. However, it can be methylated to P(CF3)(3)CH3+.

引用

页码：6083 / 6085

页数：3

共 50 条

[1] TRIS(TRIFLUOROMETHYL)PHOSPHINE SULPHIDE (CF3)3PS
CAVELL, RG
EMELEUS, HJ
JOURNAL OF THE CHEMICAL SOCIETY, 1964, S : 5896 - &
[2] STRUCTURE OF CH3 AND CF3
MOROKUMA, K
PEDERSEN, L
KARPLUS, M
JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (10): : 4801 - &
[3] The structure of tris(trifluoromethyl)tellurium fluoride dimethylformamide, [Te(CF3)3•DMF(μ-F)]∞
Kirij, Natalya V.
Yagupolskii, Yurii L.
Tyrra, Wieland
Pantenburg, Ingo
Naumann, Dieter
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (07): : 943 - 945
[4] PREPARATION AND PROPERTIES OF BIS-TRIS(TRIFLUOROMETHYL)GERMYL CHALCOGENIDES - (CF3)3GE-TE-GE(CF3) (CF3)GE-3-O-GE(CF3)3, NCF3)GE-3-S-GE(CF3), (CF3), (CF3)GE-3-SE-GE(CF3)3 MOLECULAR-STRUCTURE OF [(CF3)3GE]O-2
EUJEN, R
LAUFS, FE
OBERHAMMER, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 561 (06): : 82 - 98
[5] VIBRATIONAL SPECTRA AND STRUCTURE OF TRIS-BIS-TRIFLUOROMETHYL-PHOSPHINO-AMINE, N P(CF3)2!3
HENDRA, PJ
JOHNS, RA
MILES, CTS
VEAR, CJ
BURG, AB
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1970, A 26 (11): : 2169 - &
[6] EXCHANGE-REACTIONS BETWEEN O-NITROSOBIS(TRIFLUOROMETHYL)HYDROXYLAMINE AND P(CF3)3,AS(CF3)3,SB(CF3)3
ANG, HG
SO, KK
JOURNAL OF FLUORINE CHEMISTRY, 1985, 27 (04) : 411 - 432
[7] AN ALTERNATIVE ROUTE FOR THE SYNTHESIS OF TRIS(TRIFLUOROMETHYL)BISMUTH, BI(CF3)3
NAUMANN, D
SCHLENGERMANN, R
TYRRA, W
JOURNAL OF FLUORINE CHEMISTRY, 1994, 66 (01) : 79 - 80
[8] ELECTRON-DIFFRACTION INVESTIGATION OF MOLECULAR STRUCTURE OF TRIS(TRIFLUOROMETHYL)METHANE, (CF3) 3CH, IN VAPOR-PHASE
STOLEVIK, R
THOM, E
ACTA CHEMICA SCANDINAVICA, 1971, 25 (09): : 3205 - &
[9] NOVEL REACTIONS INVOLVING O-NITROSOBIS(TRIFLUOROMETHYL)HYDROXYLAMINE WITH P(CF3)3, AS(CF3)3, AND SB(CF3)3 AND SOME OLEFINS
ANG, HG
SO, KK
JOURNAL OF FLUORINE CHEMISTRY, 1983, 22 (01) : 95 - 98
[10] PREPARATION AND CHARACTERIZATION OF TRIPHOSPHOLENE COMPLEXES OF ZEROVALENT PLATINUM - CRYSTAL AND MOLECULAR-STRUCTURE OF [PT((CF3)P(CF3)PP(CF3)PC(CF3)=C(CF3))(PPH3)2]
PHILLIPS, IG
BALL, RG
CAVELL, RG
INORGANIC CHEMISTRY, 1987, 26 (24) : 4074 - 4079

← 1 2 3 4 5 →