Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis

被引：142

作者：

Ghaffari, Behnaz ^{[1
]}

Preshlock, Sean M. ^{[1
]}

Plattner, Donald L. ^{[1
]}

Staples, Richard J. ^{[1
]}

Maligres, Peter E. ^{[2
]}

Krska, Shane W. ^{[2
]}

Maleczka, Robert E., Jr. ^{[1
]}

Smith, Milton R., III ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

[2] Merck Res Labs, Dept Proc Chem, Rahway, NJ 07065 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 41期

基金：

美国国家科学基金会;

关键词：

DIRECTED ORTHO BORYLATION; C-H ACTIVATION; FUNCTIONALIZED ARENES; IRIDIUM; COMPLEXES; DERIVATIVES;

D O I：

10.1021/ja506229s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.

引用

页码：14345 / 14348

页数：4

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