Aminolysis of Aryl Ester Using Tertiary Amine as Amino Donor via C-O and C-N Bond Activations

被引：68
作者：
Bao, Yong-Sheng [1 ]
Zhaorigetu, Bao [1 ]
Agula, Bao [1 ]
Baiyin, Menghe [1 ]
Jia, Meilin [1 ]
机构：
[1] Inner Mongolia Normal Univ, Inner Mongolia Key Lab Green Catalysis, Coll Chem & Environm Sci, Hohhot 010022, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 02期
关键词：
CATALYZED OXIDATIVE CYANATION; CROSS-COUPLING REACTIONS; ORGANOBORON COMPOUNDS; ALLYLIC ALKYLATIONS; MOLECULAR-OXYGEN; SODIUM-CYANIDE; CLEAVAGE; CARBOXYLATES; COMPLEXES; ALDEHYDES;
D O I：
10.1021/jo4023974
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of a broad scope of tertiary amides under neutral and mild conditions. The mechanism may undergo the two key steps of oxidative addition of acyl C-O bond in parent ester and C-N bond cleavage of tertiary amine via an iminium-type intermediate.
引用
收藏
页码：803 / 808
页数：6
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