The art of using ionic liquids in the synthesis of inorganic nanomaterials

被引:145
作者
Duan, Xiaochuan [1 ]
Ma, Jianmin [2 ]
Lian, Jiabiao [3 ]
Zheng, Wenjun [1 ]
机构
[1] Nankai Univ, Coll Chem, Dept Chem Mat, Key Lab Adv Energy Mat Chem & TKL Met & Mol Based, Tianjin 300071, Peoples R China
[2] Hunan Univ, Key Lab Micronano Optoelect Devices, Minist Educ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
[3] Chinese Univ Hong Kong, Dept Phys, Hong Kong, Hong Kong, Peoples R China
基金
中国国家自然科学基金;
关键词
IONOTHERMAL SYNTHESIS; PRECURSOR ILP; PHOTOCATALYTIC ACTIVITY; HYDROTHERMAL SYNTHESIS; HOLLOW MICROSPHERES; FORMATION MECHANISM; ASSISTED SYNTHESIS; ROUTE; NANOSTRUCTURES; NANOPARTICLES;
D O I
10.1039/c3ce41203b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Wet chemistry using ionic liquids as the medium has proven to be highly efficient for the preparation of several types of metallic, metal oxides, and other kinds of semiconductor nanostructures, and so on. This article reviews state-of-the-art research activities in the field, focusing on the use of ionic liquids as a versatile regent for the synthesis of various nanoparticle systems. We begin with a survey of choices to explore the ability of ionic liquids to act as a reactant, solvent, and surfactant, as a function of other synthesis parameters, also denoted as ionic liquid precursors (or task-special ionic liquids), which offer many advantages over traditional solution-phase methods. We then examine the design and fabrication of functional inorganic materials by means of optimizing the effect models of ionic liquids. Many of the most recent advances in ionothermal or ionic liquid-assisted synthesis have been realized by appropriate choice of cations or anions of ionic liquids according to the need. This review also highlights crucial issues that should be addressed in future research activities.
引用
收藏
页码:2550 / 2559
页数:10
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