Crystallization and characterization of nonlinear optical l-histidinium dihydrogen orthophosphate orthophosporic acid single crystal

被引：7

作者：

Madhavan, J.

Aruna, S.

Ambujam, K.

Pragasam, A. Joseph Arul

Ravikumar, S. M.

Mohamed, M. Gulam

Sagayaraj, P. ^{[1
]}

机构：

[1] Loyola Coll, Dept Phys, Madras 4, Tamil Nadu, India

[2] Queen Marys Coll, Dept Phys, Madras 600004, Tamil Nadu, India

[3] Sathyabama Inst Sci & Technol, Dept Phys, Madras 600119, Tamil Nadu, India

[4] New Coll, Dept Phys, Madras 600013, Tamil Nadu, India

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 2006年 / 41卷 / 10期

关键词：

NLO; single crystal; solution growth; thermal analysis; dielectric constant;

D O I：

10.1002/crat.200610710

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

L-histidinium dihydrogen orthophosphate orthophosporic acid (abbreviated as LHP) with molecular formula C6H10N3O2 center dot+H2PO4 center dot-H3PO4 was successfully grown by slow evaporation technique from aqueous solution. The crystal was characterized by X-ray diffractometry (XRD), UV-Vis-NIR, TGA, DTA, microhardness and solubility studies. The dielectric constant and dielectric loss of the crystal were studied as function of frequency. Photoconductivity studies were also carried out on the sample. The SHG efficiency of the crystal is studied using the Kurtz and Perry technique. (C) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：997 / 1001

页数：5

共 18 条

[1] BALAREW C, 1984, J SOLID STATE CHEM, V55, P1, DOI 10.1016/0022-4596(84)90240-8
[2] BELT RF, 1985, LAS FOCUS-ELECTRO-OP, V21, P110
[3] BENETT L, 1970, ACTA CRYSTALLOGR B, V26, P1722
[4] HYDROGEN-BONDING AND THERMAL VIBRATIONS IN CRYSTALLINE PHOSPHATE SALTS OF HISTIDINE AND IMIDAZOLE
BLESSING, RH
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1986, 42 : 613 - 621
[5] Calark R.S., 1988, PHOTONIC SPECTRA, V22, P135
[6] THE CRYSTAL STRUCTURE OF HISTIDINE HYDROCHLORIDE MONOHYDRATE
DONOHUE, J
LAVINE, LR
ROLLETT, JS
[J]. ACTA CRYSTALLOGRAPHICA, 1956, 9 (07): : 655 - 662
[7] Infrared vibrational spectra of L-histidinium dihydrogen orthophosphate orthophosphoric acid (LHP)
Espinosa, E
Wyncke, B
Brehat, F
Gerbaux, X
Veintemillas, S
Molins, E
[J]. INFRARED PHYSICS & TECHNOLOGY, 1997, 38 (07) : 449 - 458
[8] Gambino R.J., 1990, B MAT RES SOC, V15, P20
[9] Growth and characterisation of L-arginine diphosphate crystal
Ittyachan, R
Sagayaraj, P
[J]. JOURNAL OF CRYSTAL GROWTH, 2002, 243 (02) : 356 - 360
[10] Joshi VN., 1990, Photoconductivity

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