Inhibiting evaluation of β-Cyclodextrin-modified acrylamide polymer on alloy steel in sulfuric solution

被引:58
作者
Zou, Changjun [1 ]
Yan, Xueling [1 ]
Qin, Yibie [1 ]
Wang, Meng [1 ]
Liu, Yuan [1 ]
机构
[1] Southwest Petr Univ, Coll Chem & Chem Engn, Chengdu 610500, Peoples R China
基金
中国国家自然科学基金;
关键词
Alloy; Polymer; EIS; Polarization; SEM; Acid inhibition; GREEN CORROSION-INHIBITOR; MILD-STEEL; HYDROCHLORIC-ACID; CARBON-STEEL; POLYACRYLIC-ACID; BEHAVIOR; ALUMINUM; SURFACTANTS; DERIVATIVES; TERPOLYMER;
D O I
10.1016/j.corsci.2014.04.046
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The inhibiting performance of beta-Cyclodetrin-modified acrylamide polymer (poly(AM-co-A-beta-CD-co-NaAA)) on X70 steel in 0.5 M H2SO4 solution has been investigated using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The polarization curves results reveal that polymer acts as a mixed-type inhibitor. The inhibition efficiency is found to increase by increasing the polymer concentration up to maximum 84.9% for 150 mg L-1 at 303 K. The adsorption is confirmed to obey the Langmuir isotherm. The SEM and EDS results demonstrate that X70 surface is protected by beta-Cyclodextrin-modified acrylamide polymer. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:445 / 454
页数:10
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