Selectfluor-mediated benzo[d][1,2,3]triazole functionalisation of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene

被引：3
作者：
Li, Xiaofang [1 ]
Fu, Xinliang [1 ]
Huang, Yulin [1 ]
Yan, Zhiyong [2 ]
机构：
[1] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Key Lab Theoret Organ Chem & Funct Mol, Minist Educ, Xiangtan 411201, Hunan, Peoples R China
[2] Jiaxing Univ, Coll Mat & Text Engn, Jiaxing 314001, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2018年 / 04期
基金：
中国国家自然科学基金;
关键词：
1H-benzo[d][1,2,3]triazole; 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene; Selectfluor; NORCORROLE; BODIPYS; SYSTEM; RING;
D O I：
10.3184/174751918X15233557008107
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
8-Aryl-1-(1H-benzo[d][1,2,3]triazole-yl)-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene and 8-aryl-3,5-di-(1H-benzo[d][1,2,3]triazole-yl)4,4-difluoro-4-bora-3a,4a-diaza-s-indacene derivatives were synthesised by the reaction of 4,4-difluoro-4-bora-3a, 4a-diaza-s-indacene with benzo[d][1,2,3]triazole in the presence of Selectfluor in moderate to good yields. The reaction took placed regioselectively on the 3(5)-position carbon of 4,4-difluoro-4-bora-3a, 4a-diaza-s-indacene, which was confirmed by X-ray analysis.
引用
收藏
页码：202 / 205
页数：4
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