Controlled conversion of polyacrylamide into polyacrylic acid

被引：2

作者：

Bicak, N

Acikkaya, N

Koza, G

机构：

[1] Istanbul Technical University, Department of Chemistry, Maslak

来源：

POLYMER BULLETIN | 1997年 / 39卷 / 04期

关键词：

poly(acrylamide); poly(acrylic acid co-acrylamide); poly(acrylic acid); nitrous acid reaction;

D O I：

10.1007/s002890050173

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Interaction of nitrous acid with aqua solution of poly(acrylamide) gives poly(acrylic acid) in quantitative conversion yields. The reaction proceeds smoothly, with simultaneous evolution of nitrogen, provided that the temperature below 5 degrees C. The procedure presented provides a versatile route to prepare acrylic acid-acrylamide copolymers in any desired composition, by adjusting molar ratio of nitrous acid.

引用

页码：459 / 464

页数：6

共 5 条

[1]

HUMMEL DO, 1978, ATLAS POLYM PLASTIC

[2] MOLECULAR WEIGHT OF POLYACRYLIC AND POLYMETHACRYLIC ACID [J].

KATCHALSKY, A ;

EISENBERG, H .

JOURNAL OF POLYMER SCIENCE, 1951, 6 (02) :145-154

[3]

Morgan R.L., 1956, United States Patent Office, Patent No. 2775557

[4]

SMETS G, 1959, MAKROMOLEKUL CHEM, V34, P190

[5] AN INVESTIGATION OF THE RELATIONSHIP BETWEEN POLYMER STRUCTURE AND MECHANICAL PROPERTIES .3. A THERMODYNAMIC AND OPTICAL ANALYSIS OF THE BEHAVIOR OF POLYETHYLENE, POLYVINYL CHLORIDE, AND LACTOPRENE [J].

STEIN, RS ;

KRIMM, S ;

TOBOLSKY, AV .

TEXTILE RESEARCH JOURNAL, 1949, 19 (01) :8-20

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