Stepwise Assembly of Pd6(RuL3)8 Nanoscale Rhombododecahedral Metal-Organic Cages via Metalloligand Strategy for Guest Trapping and Protection

被引：282

作者：

Li, Kang ^{[1
]}

Zhang, Lu-Yin ^{[1
]}

Yan, Cheng ^{[1
]}

Wei, Shi-Chao ^{[1
]}

Pan, Mei ^{[1
]}

Zhang, Li ^{[1
]}

Su, Cheng-Yong ^{[1
,2
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Lehn Inst Funct Mat, State Key Lab Optoelect Mat & Technol,MOE Lab Bio, Guangzhou 510275, Guangdong, Peoples R China

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 12期

关键词：

MOLECULAR ARCHITECTURES; CATALYTIC KNOEVENAGEL; ORGANOMETALLIC CAGES; FRAMEWORKS; DESIGN; STABILIZATION; RELEASE;

D O I：

10.1021/ja410044r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stepwise synthesis of nanosized Pd-Ru heteronuclear metal-organic cages from predesigned redox- and photo-active Ru(II)-metalloligand and naked Pd(II) ion is described. The resulting cage shows rhombododecahedral shape and contains a 5350 angstrom(3) cavity and 12 open windows, facilitating effective trapping of both polar and nonpolar guest molecules. Protection of photosensitive guests against UV radiation is studied.

引用

页码：4456 / 4459

页数：4

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