Synthesis of substituted 2-amino-4,6-bis(nonafluoro-tert-butyl)1,3,5-triazines

被引：9
|
作者：
Popov, AV
Shastin, AV [1 ]
Luzina, EL
Pushin, AN
Gavrishova, TN
机构：
[1] Russian Acad Sci, Inst Physiol Act Subst, Chernogolovka 142432, Moscow Region, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
2-chloro-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazine; 2-(alkylamino)-4,6-bis(nonafluoro-tert-butyl); 1,3,5-triazines; nucleophilic substitution; hindered rotation; NMR; spectra;
D O I：
10.1007/BF02496410
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A procedure was developed for the synthesis of substituted 2-amino-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazines from 2-chloro-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazine and aliphatic and aromatic amines. The data of F-19 NMR spectroscopy are indicative of the presence of a barrier to internal rotation.
引用
收藏
页码：1548 / 1552
页数：5
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