Synthesis of substituted 2-amino-4,6-bis(nonafluoro-tert-butyl)1,3,5-triazines

被引：9
|
作者：
Popov, AV
Shastin, AV [1 ]
Luzina, EL
Pushin, AN
Gavrishova, TN
机构：
[1] Russian Acad Sci, Inst Physiol Act Subst, Chernogolovka 142432, Moscow Region, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
2-chloro-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazine; 2-(alkylamino)-4,6-bis(nonafluoro-tert-butyl); 1,3,5-triazines; nucleophilic substitution; hindered rotation; NMR; spectra;
D O I：
10.1007/BF02496410
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A procedure was developed for the synthesis of substituted 2-amino-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazines from 2-chloro-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazine and aliphatic and aromatic amines. The data of F-19 NMR spectroscopy are indicative of the presence of a barrier to internal rotation.
引用
收藏
页码：1548 / 1552
页数：5
相关论文
共 50 条
  • [1] Synthesis of substituted 2-amino-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazines
    A. V. Popov
    A. V. Shastin
    E. L. Luzina
    A. N. Pushin
    T. N. Gavrishova
    Russian Chemical Bulletin, 1999, 48 : 1548 - 1552
  • [2] Synthesis of 2-alkoxy-4,6-bis(trinitromethyl)-1,3,5-triazines
    Gidaspov, Alexandr A.
    Bakharev, Vladimir V.
    Kukushkin, Ivan K.
    Zalomlenkov, Vladimir A.
    Burkov, Pavel S.
    NEW TRENDS IN RESEARCH OF ENERGETIC MATERIALS, PTS I & II, 13TH SEMINAR, 2010, : 492 - 494
  • [3] SYNTHESIS AND CHARACTERIZATION OF SUBSTITUTED 2-(ARYL-AZOARYLAMINO)-4,6-DICHLOR-4,6-BIS(ARYL-AZOARYLAMINO)-1,3,5-TRIAZINES AND 2-CHLOR-4,6-BIS(ARYL-AZOARYLAMINO)-1,3,5-TRIAZINES
    BACALOGLU, R
    HAVLIK, I
    CSUNDERLIK, C
    REVUE ROUMAINE DE CHIMIE, 1984, 29 (02) : 185 - 191
  • [4] SYNTHESIS OF NITRO-1,3,5-TRIAZINES NITROSO-1,3,5-TRIAZINES AND AZOXY-1,3,5-TRIAZINES BY THE OXIDATION OF 2-HYDROXYAMINO-4,6-BIS(DIMETHYLAMINO)-1,3,5-TRIAZINE
    SEDOVA, VF
    KRIVOPALOV, VP
    MAMAEV, VP
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1987, 36 (06): : 1327 - 1328
  • [5] Mechanistic studies of photoacid generation from substituted 4,6-bis(trichloromethyl)-1,3,5-triazines
    Pohlers, G
    Scaiano, JC
    Sinta, R
    Brainard, R
    Pai, D
    CHEMISTRY OF MATERIALS, 1997, 9 (06) : 1353 - 1361
  • [6] Phytotoxicity caused by peroxidizing herbicides is alleviated by 2-substituted 4,6-bis(ethylamino)-1,3,5-triazines
    Ohki, A
    Ohki, S
    Koizumi, K
    Sato, Y
    Kohno, H
    Boger, P
    Wakabayashi, K
    JOURNAL OF PESTICIDE SCIENCE, 1997, 22 (04): : 309 - 313
  • [7] Synthesis, structural determination and dynamic behavior of 2-chloro-4,6-bis(pyrazolylamino)-1,3,5-triazines
    Díaz-Ortiz, A
    Elguero, J
    Foces-Foces, C
    de la Hoz, A
    Moreno, A
    Moreno, S
    Sánchez-Migallón, A
    Valiente, G
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (24) : 4451 - 4457
  • [8] SYNTHESIS OF SOME 2-SUBSTITUTED-4,6-DIAMINO-1,3,5-TRIAZINES
    ODA, R
    MORITA, Y
    KOGYO KAGAKU ZASSHI, 1961, 64 (04): : 659 - &
  • [9] Synthesis and Crystal Structure Analysis of 2-Amino-4,6-bis(diphenoxyl phosphoramide)-1,3,5-triazine
    Zhang Nan
    Cheng Chang-Mei
    Wang Ru-Ji
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (07) : 1042 - 1046
  • [10] Synthesis and Crystal Structure Analysis of 2-Amino-4,6-bis(diphenoxyl phosphoramide)-1,3,5-triazine
    张楠
    成昌梅
    王如骥
    结构化学, 2012, 31 (07) : 1042 - 1046
12345