A water-compatible, highly active and reusable PEG-coated mesoporous silica-supported palladium complex and its application in Suzuki coupling reactions

被引:87
|
作者
Yang, Qing
Ma, Shengming
Li, Jixue
Xiao, Fengshou
Xiong, Hai
机构
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
关键词
D O I
10.1039/b605733k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly active heterogeneous palladium catalyst was prepared from coated mesoporous materials which contain a layer of readily available PEG with a labile coordinating ability for palladium. The aqueous suspension of the catalyst may be reused several times by simple extraction of the aqueous reaction mixture with ether to remove the product.
引用
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页码:2495 / 2497
页数:3
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