The langbeinite-type barium vanadium(III) orthophosphate, Ba3V4(PO4)6

被引：8

作者：

Dross, T ^{[1
]}

Glaum, R ^{[1
]}

机构：

[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804005689

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Langbeinite-type Ba3V4(PO4)(6) has been crystallized from a stoichiometric melt starting from Ba(PO3)(2) and V2O3. The crystal structure has been refined from single-crystal X-ray diffraction data. It consists of a vanadato(III)-phosphate network [V-4(PO4)(6)](6-), which shows some resemblance to the NASICON structure type. A new method is presented for the visualization of this structural relationship. The single-crystal electronic spectrum of yellow-green Ba3V4(PO4)(6) shows the absorption bands typical for the octahedral chromophore [(VO6)-O-III].

引用

页码：I58 / I60

页数：3

共 30 条

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