Synthesis of an Amine-Oleate Derivative Using an Ionic Liquid Catalyst

被引：26

作者：

Biswas, Atanu ^{[1
]}

Sharma, Brajendra K. ^{[2
,3
]}

Doll, Kenneth M. ^{[2
]}

Erhan, Sevim Z. ^{[4
]}

Willett, Julious L. ^{[1
]}

Cheng, H. N. ^{[5
]}

机构：

[1] ARS, Plant Polymer Res Unit, Natl Ctr Agr Utilizat Res, USDA, Peoria, IL 61604 USA

[2] ARS, Food & Ind Oil Unit, Natl Ctr Agr Utilizat Res, USDA, Peoria, IL 61604 USA

[3] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA

[4] ARS, Eastern Reg Res Ctr, USDA, Wyndmoor, PA 19038 USA

[5] Ashland Hercules Water Technol, Wilmington, DE 19808 USA

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 2009年 / 57卷 / 18期

关键词：

Epoxidized methyl oleate; aniline; branched oleochemical; lubrication fluid; SOYBEAN OIL; VEGETABLE-OILS; CYCLIC ACETALS; METHYL OLEATE; EPOXIDATION; OXIDATION; ESTER; KINETICS;

D O I：

10.1021/jf901401s

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

A facile (and environmentally friendly) reaction between epoxidized methyl oleate and aniline to produce an oleate-aniline adduct, without the formation of fatty amide, was discovered. This reaction was carried out neat, with a catalytic amount of an ionic liquid. No solvent was used, no byproducts were produced, and the ionic liquid could be recovered and recycled. The reaction products were fully characterized by NMR and GC-MS.

引用

页码：8136 / 8141

页数：6

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