Synthesis of an Amine-Oleate Derivative Using an Ionic Liquid Catalyst

被引：26

作者：

Biswas, Atanu ^{[1
]}

Sharma, Brajendra K. ^{[2
,3
]}

Doll, Kenneth M. ^{[2
]}

Erhan, Sevim Z. ^{[4
]}

Willett, Julious L. ^{[1
]}

Cheng, H. N. ^{[5
]}

机构：

[1] ARS, Plant Polymer Res Unit, Natl Ctr Agr Utilizat Res, USDA, Peoria, IL 61604 USA

[2] ARS, Food & Ind Oil Unit, Natl Ctr Agr Utilizat Res, USDA, Peoria, IL 61604 USA

[3] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA

[4] ARS, Eastern Reg Res Ctr, USDA, Wyndmoor, PA 19038 USA

[5] Ashland Hercules Water Technol, Wilmington, DE 19808 USA

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 2009年 / 57卷 / 18期

关键词：

Epoxidized methyl oleate; aniline; branched oleochemical; lubrication fluid; SOYBEAN OIL; VEGETABLE-OILS; CYCLIC ACETALS; METHYL OLEATE; EPOXIDATION; OXIDATION; ESTER; KINETICS;

D O I：

10.1021/jf901401s

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

A facile (and environmentally friendly) reaction between epoxidized methyl oleate and aniline to produce an oleate-aniline adduct, without the formation of fatty amide, was discovered. This reaction was carried out neat, with a catalytic amount of an ionic liquid. No solvent was used, no byproducts were produced, and the ionic liquid could be recovered and recycled. The reaction products were fully characterized by NMR and GC-MS.

引用

页码：8136 / 8141

页数：6

共 40 条

[1] Novel modified soybean oil containing hydrazino-ester: synthesis and characterization
Biswas, Atanu
Sharma, Brajendra K.
Willet, J. L.
Vermillion, K.
Erhan, Sevim Z.
Cheng, H. N.
[J]. GREEN CHEMISTRY, 2007, 9 (01) : 85 - 89
[2] Decision criteria consolidation: A theoretical foundation of Pareto Principle to Porter's Competitive Forces
Chen, JCH
Chong, PP
Chen, YS
[J]. JOURNAL OF ORGANIZATIONAL COMPUTING AND ELECTRONIC COMMERCE, 2001, 11 (01) : 1 - 14
[3] TRENDS IN SHIFT RULES IN C-13 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY AND COMPUTER-AIDED SHIFT PREDICTION
CHENG, HN
BENNETT, MA
[J]. ANALYTICA CHIMICA ACTA, 1991, 242 (01) : 43 - 56
[4] Soybean oil microernulsions with oleic acid/glycols as cosurfactants
Comelles, F
Sánchez-Leal, J
González, JJ
[J]. JOURNAL OF SURFACTANTS AND DETERGENTS, 2005, 8 (03) : 257 - 262
[5] Conversion of methyl oleate to branched-chain derivatives
Dailey, Oliver D., Jr.
Prevost, Nicolette
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2007, 84 (06) : 565 - 571
[6] DANIELLS S, 2006, SCI NUTR FATS O 1128
[7] DEGUZMAN D, 2004, CHEM MARKET REPORTER, V266, P1
[8] DEMBITSKY VM, 2008, INFORM, V19, P577
[9] The development and characterisation of triglyceride-based 'spontaneous' multiple emulsions
Devani, MJ
Ashford, M
Craig, DQM
[J]. INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2005, 300 (1-2) : 76 - 88
[10] Synthesis of cyclic acetals (ketals) from oleochemicals using a solvent free method
Doll, Kenneth M.
Erhan, Sevim Z.
[J]. GREEN CHEMISTRY, 2008, 10 (06) : 712 - 717

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