Generation and synthetic uses of stable 4-[2-isopropylidene]-phenol carbocation from bisphenol A

被引：44

作者：

Chen, WF ^{[1
]}

Lin, HY ^{[1
]}

Dai, SA ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem Engn, Taichung 402, Taiwan

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 14期

关键词：

D O I：

10.1021/ol0493305

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stable 4-[2-isopropylidene]-phenol carbocation, IPP cation 1, was generated readily by addition of bisphenol A in concentrated sulfuric acid at ambient temperature, and the cation could be used for facile syntheses of 4-isopropenyl phenol (IPP), IPP dimers, and spiro-bisphenol derivatives.

引用

页码：2341 / 2343

页数：3

共 14 条

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