2D NMR Spectroscopic Study of Lignin from Triticum sp and Larix sibirica

被引:7
作者
Belyi, V. A. [1 ]
Karmanov, A. P. [2 ]
Kocheva, L. S. [3 ]
机构
[1] Russian Acad Sci, Inst Chem, Ural Branch, Komi Sci Ctr, Syktyvkar 167982, Russia
[2] Russian Acad Sci, Inst Biol, Ural Branch, Komi Sci Ctr, Syktyvkar 107982, Russia
[3] Russian Acad Sci, Inst Geol, Ural Branch, Komi Sci Ctr, Syktyvkar 167982, Russia
关键词
Triticum sp lignin; Larix sibirica lignin; 2D NMR spectroscopy; chemical structure; MACROMOLECULES; DIBENZODIOXOCINS;
D O I
10.1007/s10600-015-1450-1
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
Lignins isolated from Larix sibirica wood and Triticum sp. straw were investigated using 2D NMR spectroscopy. Various structural fragments of the macromolecules were identified. The chemical structures of the two lignins were compared. Quantitative ratios of guaiacyl, syringyl, and p-coumaryl structural units were found. Dibenzodioxocine structures were noted in wood lignin, in contrast with wheat lignin. This confirmed the concept of linear wheat lignin macromolecules.
引用
收藏
页码:929 / 933
页数:5
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