A novel method to produce Pd nanoparticle ink for ink-jet printing technology

被引:32
作者
Tseng, Chun-Chieh [2 ]
Chang, Chang-Pin [1 ]
Sung, Yuh [3 ]
Chen, Yann-Cheng [1 ]
Ger, Ming-Der [1 ]
机构
[1] Natl Def Univ, Chung Cheng Inst Technol, Dept Appl Chem & Mat Sci, Tao Yuan 335, Taiwan
[2] Natl Def Univ, Chung Cheng Inst Technol, Grad Sch Def Sci, Tao Yuan 335, Taiwan
[3] Chung Shan Inst Sci & Technol, Chem Syst Res Div, Tao Yuan 335, Taiwan
关键词
Catalytic ink; Electroless plating; Ink-jet printing; ACTIVATOR;
D O I
10.1016/j.colsurfa.2009.02.026
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel method for the preparation of ink-jet printing ink with palladium (Pd) nanoparticles reduced by styrene (St) oligomers is presented in this study. The noble metal nanoparticles reduced and stabilized by styrene oligomer showed their well dispersion in the organic solvent without surfactant and reductant in the mixture. These Pd nanoparticles can be used as activator for electroless metal deposition. The deposition rate of St/Pd nanoparticles system was higher than that of conventional Sn/Pd colloids. It is an indication that the catalytic activity of St/Pd is better than Sn/Pd colloids. The ink based on St/Pd colloids was successfully ink-jet printed onto a flexible substrate. The formed metallic palladium patterns were subjected to electroless nickel plating, yielding well-defined nickel lines at low temperature. The properties of Pd nanoparticle ink and kinetics of electroless nickel deposition (EN) were characterized by transmission electron microscopy (TEM), quartz crystal microbalance (QCM), four-point probe, mixed potential theory (MPT) and scanning electron microscopy (SEM), respectively. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:206 / 210
页数:5
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