New photoluminescent Cu(I)N4 chromophores.: Stabilisation of copper(I) by unconjugated diimines

被引:47
作者
Chowdhury, S
Patra, GK
Drew, MGB
Chattopadhyay, N
Datta, D [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India
[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England
[3] Jadavpur Univ, Dept Chem, Calcutta 700032, W Bengal, India
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 03期
关键词
D O I
10.1039/a909224b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new photoluminescent homoleptic distorted tetrahedral (CuN4)-N-I chromophores with Cu-II/I potentials of 0.66-0.81 V vs. SCE are isolated by using two unconjugated diimines (2:1 condensates of R1R2C=O and ethylenediamine; R-1=Ph, R-2=H; R-1=R-2=Ph) as ligands.
引用
收藏
页码:235 / 237
页数:3
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