A photoactive bimetallic framework for direct aminoformylation of nitroarenes

被引:44
作者
Baig, R. B. Nasir [1 ]
Verma, Sanny [1 ]
Nadagouda, Mallikarjuna N. [2 ]
Varma, Rajender S. [1 ]
机构
[1] US EPA, Natl Risk Management Res Lab, Sustainable Technol Div, MS 443, Cincinnati, OH 45268 USA
[2] US EPA, Natl Risk Management Res Lab, WSWRD, WQMB, MS 443, Cincinnati, OH 45268 USA
关键词
GRAPHITIC CARBON NITRIDE; TRANSFER HYDROGENATION; EFFICIENT; TEMPERATURE; REDUCTION; OXIDATION; CATALYST; AMINES;
D O I
10.1039/c5gc02799c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A bimetallic catalyst, AgPd@g-C3N4, synthesized by reducing silver and palladium salts over graphitic carbon nitride (g-C3N4), enables the concerted reductive formylation of aromatic nitro compounds under photo-chemical conditions using formic acid, which serves the dual role of a hydrogen source and a formylating agent.
引用
收藏
页码:1019 / 1022
页数:4
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