Reaction of metallocenes with maleic anhydride

被引:3
作者
Puzin, Yu. I. [1 ]
Gafurov, M. A. [2 ]
机构
[1] Ufa State Petr Technol Univ, Ufa 450062, Russia
[2] Pilot Plant Neftekhim, Ufa, Russia
关键词
maleic anhydride; ferrocene; titanocene dichloride; zirconocene dichloride; coordination complex formation; charge transfer complex; FREE-RADICAL POLYMERIZATION; METHYL-METHACRYLATE; TITANOCENE DICHLORIDE; FERROCENE;
D O I
10.1134/S1070363215100187
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Spectral investigation applying UV, IR, and H-1 NMR techniques to the reaction of ferrocene, titano- and zirconocene dichlorides with maleic anhydride was carried out. It was found that in all cases charge transfer complexes were formed. It was showed that the structure of the metallocene affected both the process of the formation and structure of the complexes.
引用
收藏
页码:2334 / 2337
页数:4
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