Pentacenobis(thiadiazole)dione, an n-Type Semiconductor for Field-Effect Transistors

被引：16

作者：

Shi, Zi-Fa ^{[1
,2
,3
,4
]}

Black, Hayden T. ^{[1
,2
]}

Dadvand, Afshin ^{[1
,2
]}

Perepichka, Dmitrii F. ^{[1
,2
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 0B8, Canada

[2] McGill Univ, Ctr Self Assembled Chem Struct, Montreal, PQ H3A 0B8, Canada

[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[4] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 12期

基金：

美国国家科学基金会; 加拿大自然科学与工程研究理事会;

关键词：

THIN-FILM TRANSISTORS; LINEARLY FUSED RINGS; ORGANIC SEMICONDUCTORS; CHARGE-TRANSPORT; SINGLE-CRYSTALS; ACENES; PENTACENE; HEPTACENE; MOBILITY; HETEROACENES;

D O I：

10.1021/jo500760c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new heteroacenequinone, pentaceno[2,3-c:9,10-c']bis([1,2,5]thiadiazole)-6,13-dione (PBTDQ), with two peripheral thiadiazole rings was synthesized, and its solid-state properties were characterized. The fused planar structure with a low-lying LUMO and low reorganization energy facilitates electron transport, affording mu(e) values of up to 0.11 cm(2) V-1 s(-1) in field-effect transistor devices.

引用

页码：5858 / 5860

页数：3

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