Pentacenobis(thiadiazole)dione, an n-Type Semiconductor for Field-Effect Transistors

被引：16
作者：
Shi, Zi-Fa [1 ,2 ,3 ,4 ]
Black, Hayden T. [1 ,2 ]
Dadvand, Afshin [1 ,2 ]
Perepichka, Dmitrii F. [1 ,2 ]
机构：
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 0B8, Canada
[2] McGill Univ, Ctr Self Assembled Chem Struct, Montreal, PQ H3A 0B8, Canada
[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[4] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 12期
基金：
美国国家科学基金会; 加拿大自然科学与工程研究理事会;
关键词：
THIN-FILM TRANSISTORS; LINEARLY FUSED RINGS; ORGANIC SEMICONDUCTORS; CHARGE-TRANSPORT; SINGLE-CRYSTALS; ACENES; PENTACENE; HEPTACENE; MOBILITY; HETEROACENES;
D O I：
10.1021/jo500760c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new heteroacenequinone, pentaceno[2,3-c:9,10-c']bis([1,2,5]thiadiazole)-6,13-dione (PBTDQ), with two peripheral thiadiazole rings was synthesized, and its solid-state properties were characterized. The fused planar structure with a low-lying LUMO and low reorganization energy facilitates electron transport, affording mu(e) values of up to 0.11 cm(2) V-1 s(-1) in field-effect transistor devices.
引用
收藏
页码：5858 / 5860
页数：3
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