Water soluble octa-functionalized POSS: all-click chemistry synthesis and efficient host guest encapsulation

被引：57

作者：

Han, Jin ^{[1
,2
]}

Zheng, Yaochen ^{[1
,3
]}

Zheng, Shuai ^{[1
]}

Li, Sipei ^{[1
]}

Hu, Tiannan ^{[1
]}

Tang, Aijin ^{[1
]}

Gao, Chao ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Polymer Sci & Engn, MOE Key Lab Macromol Synth & Functionalizat, Hangzhou 310027, Peoples R China

[2] Ningbo Inst Mat Technol & Engn CAS, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China

[3] Yantai Univ, Coll Chem & Chem Engn, Yantai 264005, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 63期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

SEGMENTED HYPERBRANCHED POLYMERS; SHAPE AMPHIPHILES; MICELLES;

D O I：

10.1039/c4cc01956c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of water soluble octa-functionalized POSSs were facilely synthesized via thiol-ene and Menschutkin click chemistry. Among them, octa-alkynyl POSS further reacted with azide-terminal alkyl long chains, resulting in a well-defined, amphiphilic octopus-like POSS. For the first time it was used for host-guest encapsulation and it exhibited an ultrahigh loading capability.

引用

页码：8712 / 8714

页数：3

共 28 条

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