Hydrogen-Bonding Catalysis: Mild and Highly Chemoselective Oxidation of Sulfides

被引：32

作者：

Russo, Alessio ^{[1
]}

Lattanzi, Alessandra ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim, I-84084 Fisciano, Italy

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 04期

关键词：

chemoselectivity; hydrogen bonds; oxidation; sulfoxides; thioureas; TERT-BUTYL HYDROPEROXIDE; ASYMMETRIC OXIDATION; METAL-FREE; CHIRAL SULFOXIDES; PEROXIDE; ACID; ORGANOCATALYSIS; CONVENIENT; NITROALKENES; EPOXIDATION;

D O I：

10.1002/adsc.200900020

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

N,N'-Bis[3,5-bis(trifluoromethyl)phenyl]thiourea, employed at only 1 mol% loading, was found to be a very effective catalyst for the oxidation of sulfides with tert-butyl hydroperoxide (TBHP), affording the sulfoxides in high yield, excellent chemoselectivity, fairly good diastereoselectivity.

引用

页码：521 / 524

页数：4

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