Click approaches in sol-gel chemistry

被引:22
作者
Cattoen, Xavier [1 ,2 ,3 ]
Noureddine, Achraf [1 ]
Croissant, Jonas [1 ]
Moitra, Nirmalya [1 ]
Buerglova, Kristyna [1 ,4 ]
Hodacova, Jana [4 ]
de los Cobos, Olivia [5 ]
Lejeune, Martine [5 ]
Rossignol, Fabrice [5 ]
Toulemon, Delphine [6 ]
Begin-Colin, Sylvie [6 ]
Pichon, Benoit P. [6 ]
Raehm, Laurence [1 ]
Durand, Jean-Olivier [1 ]
Man, Michel Wong Chi [1 ]
机构
[1] UM1, ENSCM, UM2, Inst Charles Gerhardt Montpellier,UMR CNRS 5253, F-34296 Montpellier, France
[2] Univ Grenoble Alpes, Inst NEEL, F-38042 Grenoble, France
[3] CNRS, Inst NEEL, F-38042 Grenoble, France
[4] Inst Chem Technol, Dept Organ Chem, Prague 16628 6, Czech Republic
[5] CEC, UMR CNRS 7315, Lab Sci Proc Ceram & Traitements Surface SPCTS, F-87068 Limoges, France
[6] ECPM, UdS, CNRS, Inst Phys & Chim Mat Strasbourg,UMR 7504, F-67034 Strasbourg 2, France
关键词
Sol-gel; Click chemistry; CuAAC; Organosilanes; Nanoparticles; MESOPOROUS SILICA NANOPARTICLES; SELF-ASSEMBLED MONOLAYERS; BRIDGED SILSESQUIOXANES; TERMINAL ALKYNES; MICRODOT ARRAYS; COMPLEXES; CATALYSIS; CYCLOADDITION; LOADINGS; DENSITY;
D O I
10.1007/s10971-013-3155-x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The combination of the copper-catalyzed alkyne-azide cycloaddition (CuAAC) reaction with sol-gel processing enables the versatile preparation of sol-gel materials under different shapes with targeted functionalities through a diversity-oriented approach. In this account, the development of the CuAAC reaction under anhydrous conditions for the synthesis of sol-gel precursors and for the assembling of magnetic nanoparticles on self-assembled monolayers is related, as well as the use of the classical CuAAC methodologies for the functionalization of mesoporous silica nanoparticles and microdots arrays. Coupling CuAAC and Sol-Gel will result in simplified preparations of multifunctional materials with controlled morphologies.
引用
收藏
页码:245 / 253
页数:9
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