Effect of Pt-Pd hybrid nano-particle on CdS's activity for water splitting under visible light

被引：34

作者：

Li, Xiying ^{[1
]}

Liu, Heng ^{[1
]}

Liu, Shuang ^{[1
]}

Zhang, Jing ^{[1
]}

Chen, Wei ^{[1
]}

Huang, Cunping ^{[2
]}

Mao, Liqun ^{[1
]}

机构：

[1] Henan Univ, Lab Fine Chem & Ind, Kaifeng 475004, Peoples R China

[2] Univ Cent Florida, Florida Solar Energy Ctr, Orlando, FL 32922 USA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2016年 / 41卷 / 48期

基金：

芬兰科学院;

关键词：

CdS; Pt-Pd hybrid nanoparticles; Photocatalyst; Water splitting; Hydrogen production; Photocatalytic activity; OXYGEN REDUCTION REACTION; METHANOL OXIDATION; PHOTOCATALYTIC PERFORMANCE; ELECTROCATALYTIC ACTIVITY; FUEL-CELLS; AU-PT; AT-PT; NANOPARTICLES; CATALYSTS; HOLLOW;

D O I：

10.1016/j.ijhydene.2016.11.059

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper focuses on the bi-metal co-catalyst of CdS in hydrogen generation from water splitting under visible light. Pt-Pd eutectic alloy NPs was prepared by two-step chemical reduction, and was subsequently loaded on the surface of CdS photo-catalyst by photo induced electrons when water splitting reaction was occurring under 300 W Xe light (lambda > 420 nm). According to the experimental results, the photo-activity is significantly promoted as bi-metal modified on the surface of CdS. The H-2 evolution rate of Pt-Pd/CdS, 25.28 mmol/h/gCat., is ca. 2.4 times as much as that of Pt/CdS, and 3.8 times as much as that of Pd/CdS. HRTEM/ED/EDS revealed that the so-obtained Pt-Pd hybrid NPs with a particle size of 5-8 nm is of similar twin structure. XPS revealed that the as-prepared Pt-Pd bi-metal NPs mainly composed of metallic Pt-0 and Pd-0. UV-Vis diffuse reflectance spectrum of CdS nanoparticles interpreted its trait in visible light adsorption, and PL lifetime indicated that the high active of Pt-Pd/CdS lies in its high separation efficiency. 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：23015 / 23021

页数：7

共 34 条

[1] Rationalization of Au Concentration and Distribution in AuNi@Pt Core-Shell Nanoparticles for Oxygen Reduction Reaction [J].

An, Wei ;

Liu, Ping .

ACS CATALYSIS, 2015, 5 (11) :6328-6336

[2] Structure of PtnNi Nanoparticles Electrocatalysts Investigated by X-ray Absorption Spectroscopy [J].

Bao, Hongliang ;

Li, Jiong ;

Jiang, Luhua ;

Shang, Mingfeng ;

Zhang, Shuo ;

Jiang, Zheng ;

Wei, Xiangjun ;

Huang, Yuying ;

Sun, Gongquan ;

Wang, Jian-Qiang .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (40) :20584-20591

[3] Preparation, characterization, and photocatalytic performance of NdPW12O40/TiO2 composite catalyst [J].

Cai Tiejun ;

Yue Ming ;

Wang Xianwen ;

Deng Qian ;

Peng Zhenshan ;

Zhou Wenhui .

CHINESE JOURNAL OF CATALYSIS, 2007, 28 (01) :10-16

[4] Synthesis of Pt-based hollow nanoparticles using carbon-supported Co@Pt and Ni@Pt core-shell structures as templates: Electrocatalytic activity for the oxygen reduction reaction [J].

Cantane, D. A. ;

Oliveira, F. E. R. ;

Santos, S. F. ;

Lima, F. H. B. .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 136 :351-360

[5] Highly active nanoporous Pt-based alloy as anode and cathode catalyst for direct methanol fuel cells [J].

Chen, Xiaoting ;

Jiang, Yingying ;

Sun, Junzhe ;

Jin, Chuanhong ;

Zhang, Zhonghua .

JOURNAL OF POWER SOURCES, 2014, 267 :212-218

[6] Enhanced performance of Pt and Pt-Ru supported PEDOT-RGO nanocomposite towards methanol oxidation [J].

Dinesh, Bose ;

Saraswathi, Ramiah .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (31) :13448-13458

[7] Facile Synthesis of Bimetallic Au-Pt, Pd-Pt, and Au-Pd Nanostructures: Enhanced Catalytic Performance of Pd-Pt Analogue towards Fuel Cell Application and Electrochemical Sensing [J].

Dutta, Soumen ;

Ray, Chaiti ;

Sarkar, Sougata ;

Roy, Anindita ;

Sahoo, Ramkrishna ;

Pal, Tarasankar .

ELECTROCHIMICA ACTA, 2015, 180 :1075-1084

[8] Improvement of photocatalytic activity of silver nanoparticles by radio frequency oxygen plasma irradiation [J].

Fang, Yingcui ;

Zhang, Bing ;

Hong, Liu ;

Yao, Damao ;

Xie, Zhiqiang ;

Jiang, Yang .

NANOTECHNOLOGY, 2015, 26 (29)

[9] PtNi nanoparticles embedded in porous silica microspheres as highly active catalysts for p-nitrophenol hydrogenation to p-aminophenol [J].

Guan, Huijuan ;

Chao, Cong ;

Lu, Yanjie ;

Shang, Huishan ;

Zhao, Yafei ;

Yuan, Siguo ;

Zhang, Bing .

JOURNAL OF CHEMICAL SCIENCES, 2016, 128 (09) :1355-1365

[10] Size-controllable synthesis of ultrafine PtNi nanoparticles uniformly deposited on reduced graphene oxide as advanced anode catalysts for methanol oxidation [J].

Hao, Yanfei ;

Wang, Xudan ;

Zheng, Yuanyuan ;

Shen, Jianfeng ;

Yuan, Junhua ;

Wang, Ai-jun ;

Niu, Li ;

Huang, Shengtang .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (22) :9303-9311

← 1 2 3 4 →