Efficient microwave-assisted synthesis of LiFePO4 mesocrystals with high cycling stability

被引：79
作者：
Bilecka, Idalia [1 ]
Hintennach, Andreas [2 ]
Djerdj, Igor [1 ]
Novak, Petr [2 ]
Niederberger, Markus [1 ]
机构：
[1] ETH, Dept Mat, Lab Multifunct Mat, CH-8093 Zurich, Switzerland
[2] Paul Scherrer Inst, Electrochem Lab, Dept Gen Energy, CH-5232 Villigen, Switzerland
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2009年 / 19卷 / 29期
关键词：
RECHARGEABLE LITHIUM BATTERIES; SOL-GEL ROUTE; ION BATTERIES; CATHODE MATERIAL; ELECTROCHEMICAL PERFORMANCE; SOLVOTHERMAL SYNTHESIS; TEMPERATURE; COMPOSITE; LIMNPO4; CRYSTALLIZATION;
D O I：
10.1039/b909545d
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Lithium iron phosphate mesocrystals with high cycling stability were directly synthesized within a few minutes under ambient pressure conditions using a microwave-directed nonaqueous liquid phase synthesis approach.
引用
收藏
页码：5125 / 5128
页数：4
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共 37 条
  • [1] Lithium extraction/insertion in LiFePO4:: an X-ray diffraction and Mossbauer spectroscopy study
    Andersson, AS
    Kalska, B
    Häggström, L
    Thomas, JO
    [J]. SOLID STATE IONICS, 2000, 130 (1-2) : 41 - 52
  • [2] Nanostructured materials for advanced energy conversion and storage devices
    Aricò, AS
    Bruce, P
    Scrosati, B
    Tarascon, JM
    Van Schalkwijk, W
    [J]. NATURE MATERIALS, 2005, 4 (05) : 366 - 377
  • [3] Building better batteries
    Armand, M.
    Tarascon, J. -M.
    [J]. NATURE, 2008, 451 (7179) : 652 - 657
  • [4] One-minute synthesis of crystalline binary and ternary metal oxide nanoparticles
    Bilecka, Idalia
    Djerdj, Igor
    Niederberger, Markus
    [J]. CHEMICAL COMMUNICATIONS, 2008, (07) : 886 - 888
  • [5] Kinetic and Thermodynamic Aspects in the Microwave-Assisted Synthesis of ZnO Nanoparticles in Benzyl Alcohol
    Bilecka, Idalia
    Elser, Pierre
    Niederberger, Markus
    [J]. ACS NANO, 2009, 3 (02) : 467 - 477
  • [6] Study of the effect of different synthesis routes on Li extraction-insertion from LiCoPO4
    Bramnik, NN
    Bramnik, KG
    Baehtz, C
    Ehrenberg, H
    [J]. JOURNAL OF POWER SOURCES, 2005, 145 (01) : 74 - 81
  • [7] Nanomaterials for rechargeable lithium batteries
    Bruce, Peter G.
    Scrosati, Bruno
    Tarascon, Jean-Marie
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 2930 - 2946
  • [8] Kinetic study on low-temperature synthesis of LiFePO4 via solid-state reaction
    Chang, Hao-Hsun
    Chang, Chun-Chih
    Wu, Hung-Chun
    Guo, Zheng-Zhao
    Yang, Mo-Hua
    Chiang, Yung-Ping
    Sheu, Hwo-Shuenn
    Wu, Nae-Lih
    [J]. JOURNAL OF POWER SOURCES, 2006, 158 (01) : 550 - 556
  • [9] The hydrothermal synthesis and characterization of olivines and related compounds for electrochemical applications
    Chen, Jiajun
    Vacchio, Michael J.
    Wang, Shijun
    Chernova, Natalya
    Zavalij, Peter Y.
    Whittingham, M. Stanley
    [J]. SOLID STATE IONICS, 2008, 178 (31-32) : 1676 - 1693
  • [10] Mesocrystals:: Inorganic superstructures made by highly parallel crystallization and controlled alignment
    Cölfen, H
    Antonietti, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (35) : 5576 - 5591
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