A new mixing rule for cubic equations of state and its application to vapor-liquid equilibria of polymer solutions

被引：39

作者：

Zhong, CL ^{[1
]}

Masuoka, H ^{[1
]}

机构：

[1] HIROSHIMA UNIV,FAC ENGN,DEPT CHEM ENGN,HIGASHIHIROSHIMA 739,JAPAN

来源：

FLUID PHASE EQUILIBRIA | 1996年 / 123卷 / 1-2期

关键词：

cubic equation of state; mixing rule; vapor-liquid equilibria; polymer solution;

D O I：

10.1016/S0378-3812(96)90011-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A new mixing rule for van der Waals-type two-parameter cubic equations of state (EOSs) has been proposed in this work, which is particularly suitable for highly asymmetric systems. The new mixing rule has been applied to the PRSV and SRK EOSs to calculate vapor-liquid equilibria (VLE) of polymer solutions. Compared to the other two mixing rules which have been used for VLE calculations of polymer solutions, the new mixing rule with only one temperature-independent parameter is very accurate for a wide range of temperatures. As the new mixing rule is very simple and accurate and only one temperature-independent parameter is needed, it enables the two-parameter cubic EOSs to be used in the practical calculations needed in the industrial processing of polymer solutions.

引用

页码：59 / 69

页数：11

共 31 条

[1] REPRESENTATION OF VAPOR LIQUID AND LIQUID LIQUID EQUILIBRIA FOR BINARY-SYSTEMS CONTAINING POLYMERS - APPLICABILITY OF AN EXTENDED FLORY HUGGINS EQUATION [J].

BAE, YC ;

SHIM, JJ ;

SOANE, DS ;

PRAUSNITZ, JM .

JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 47 (07) :1193-1206

[2] A STUDY OF THE THERMODYNAMIC PROPERTIES AND PHASE EQUILIBRIA OF SOLUTIONS OF POLYISOBUTENE IN NORMAL-PENTANE [J].

BAKER, CH ;

BROWN, WB ;

GEE, G ;

ROWLINSON, JS ;

STUBLEY, D ;

YEADON, RE .

POLYMER, 1962, 3 (02) :215-230

[3] HIGH POLYMER SOLUTIONS .1. VAPOUR PRESSURE OF POLYSTYRENE SOLUTIONS [J].

BAWN, CEH ;

FREEMAN, RFJ ;

KAMALIDDIN, AR .

TRANSACTIONS OF THE FARADAY SOCIETY, 1950, 46 (08) :677-684

[4] THERMODYNAMICS OF MIXTURES OF POLY(PROPYLENE OXIDE) AND BENZENE [J].

BOOTH, C ;

DEVOY, CJ .

POLYMER, 1971, 12 (05) :320-&

[5]

BOOTH C, 1971, POLYMER, V12, P309, DOI 10.1016/0032-3861(71)90053-X

[6]

BOOTH C, 1971, POLYMER, V12, P311

[7] THERMODYNAMICS OF POLYMER SOLUTIONS .2. POLYISOBUTYLENE AND BENZENE [J].

EICHINGER, BE ;

FLORY, PJ .

TRANSACTIONS OF THE FARADAY SOCIETY, 1968, 64 (548P) :2053-+

[8]

EICHINGER BE, 1972, MACROMOLECULES, V5, P1285

[9] Thermodynamics of high polymer solutions [J].

Flory, PJ .

JOURNAL OF CHEMICAL PHYSICS, 1942, 10 (01) :51-61

[10] STATISTICAL THERMODYNAMICS OF LIQUID MIXTURES [J].

FLORY, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1833-+

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