A Defect-Free Principle for Advanced Graphene Cathode of Aluminum-Ion Battery

被引：301

作者：

Chen, Hao ^{[1
]}

Guo, Fan ^{[1
]}

Liu, Yingjun ^{[1
]}

Huang, Tieqi ^{[1
]}

Zheng, Bingna ^{[1
]}

Ananth, Nimrodh ^{[1
]}

Xu, Zhen ^{[1
]}

Gao, Weiwei ^{[1
]}

Gao, Chao ^{[1
]}

机构：

[1] Zhejiang Univ, MOE Key Lab Macromol Synth & Functionalizat, Key Lab Adsorpt & Separat Mat & Technol Zhejiang, Dept Polymer Sci & Engn, 38 Zheda Rd, Hangzhou 310027, Zhejiang, Peoples R China

来源：

ADVANCED MATERIALS | 2017年 / 29卷 / 12期

基金：

中国国家自然科学基金;

关键词：

LIQUID-CRYSTALS; INTERCALATION; CARBON; FIBERS; OXIDE;

D O I：

10.1002/adma.201605958

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A conceptually new defect-free principle is proposed for designing graphene cathode of aluminum-ion battery: the fewer the defects, the better the performances. Developed through scalable approach, defect-free graphene aerogel cathode affords high capacity of 100 mAh g(-1) under an ultrahigh rate of 500 C, exceeding defective graphene and previous reports. This defect-free principle can guide us to fabricate better graphenebased electrodes.

引用

页数：8

共 49 条

[1] Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[2] Bioinspired large-scale aligned porous materials assembled with dual temperature gradients [J].

Bai, Hao ;

Chen, Yuan ;

Delattre, Benjamin ;

Tomsia, Antoni P. ;

Ritchie, Robert O. .

SCIENCE ADVANCES, 2015, 1 (11)

[3] Negative local resistance caused by viscous electron backflow in graphene [J].

Bandurin, D. A. ;

Torre, I. ;

Kumar, R. Krishna ;

Ben Shalom, M. ;

Tomadin, A. ;

Principi, A. ;

Auton, G. H. ;

Khestanova, E. ;

Novoselov, K. S. ;

Grigorieva, I. V. ;

Ponomarenko, L. A. ;

Geim, A. K. ;

Polini, M. .

SCIENCE, 2016, 351 (6277) :1055-1058

[4] Probing graphene grain boundaries with optical microscopy [J].

Dinh Loc Duong ;

Han, Gang Hee ;

Lee, Seung Mi ;

Gunes, Fethullah ;

Kim, Eun Sung ;

Kim, Sung Tae ;

Kim, Heetae ;

Quang Huy Ta ;

So, Kang Pyo ;

Yoon, Seok Jun ;

Chae, Seung Jin ;

Jo, Young Woo ;

Park, Min Ho ;

Chae, Sang Hoon ;

Lim, Seong Chu ;

Choi, Jae Young ;

Lee, Young Hee .

NATURE, 2012, 490 (7419) :235-+

[5] An Overview and Future Perspectives of Aluminum Batteries [J].

Elia, Giuseppe Antonio ;

Marquardt, Krystan ;

Hoeppner, Katrin ;

Fantini, Sebastien ;

Lin, Rongying ;

Knipping, Etienne ;

Peters, Willi ;

Drillet, Jean-Francois ;

Passerini, Stefano ;

Hahn, Robert .

ADVANCED MATERIALS, 2016, 28 (35) :7564-7579

[6] Raman spectrum of graphene and graphene layers [J].

Ferrari, A. C. ;

Meyer, J. C. ;

Scardaci, V. ;

Casiraghi, C. ;

Lazzeri, M. ;

Mauri, F. ;

Piscanec, S. ;

Jiang, D. ;

Novoselov, K. S. ;

Roth, S. ;

Geim, A. K. .

PHYSICAL REVIEW LETTERS, 2006, 97 (18)

[7] Face-to-face transfer of wafer-scale graphene films [J].

Gao, Libo ;

Ni, Guang-Xin ;

Liu, Yanpeng ;

Liu, Bo ;

Castro Neto, Antonio H. ;

Loh, Kian Ping .

NATURE, 2014, 505 (7482) :190-194

[8] A perspective on electrical energy storage [J].

Goodenough, John B. ;

Manthiram, Arumugam .

MRS COMMUNICATIONS, 2014, 4 (04) :135-142

[9] An in situ Raman study of the intercalation of supercapacitor-type electrolyte into microcrystalline graphite [J].

Hardwick, Laurence J. ;

Hahn, Matthias ;

Ruch, Patrick ;

Holzapfel, Michael ;

Scheifele, Werner ;

Buqa, Hilmi ;

Krumeich, Frank ;

Novak, Petr ;

Koetz, Ruediger .

ELECTROCHIMICA ACTA, 2006, 52 (02) :675-680

[10] Direct evidence for atomic defects in graphene layers [J].

Hashimoto, A ;

Suenaga, K ;

Gloter, A ;

Urita, K ;

Iijima, S .

NATURE, 2004, 430 (7002) :870-873

← 1 2 3 4 5 →