A biomimetic spherical cactus superhydrophobic coating with durable and multiple anti-corrosion effects

被引:107
|
作者
Zhu, Yanji [1 ,3 ]
Sun, Fenglong [3 ]
Qian, Huijuan [3 ]
Wang, Huaiyuan [2 ,3 ]
Mu, Liwen [4 ]
Zhu, Jiahua [4 ]
机构
[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300350, Peoples R China
[2] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300350, Peoples R China
[3] Northeast Petr Univ, Coll Chem & Chem Engn, Daqing 163318, Peoples R China
[4] Univ Akron, Dept Chem & Biomol Engn, Akron, OH 44325 USA
基金
中国博士后科学基金; 美国国家科学基金会;
关键词
Biomimetic structure; Polysulfone nanocomposite coating; Carbon nanotube; Superhydrophobic; Multiple corrosion resistance; Durability; CARBON NANOTUBES; CORROSION-RESISTANCE; SURFACES; FABRICATION; COMPOSITE; TRANSPARENT; WEAR; ROBUST; ALLOY; SPRAY;
D O I
10.1016/j.cej.2018.01.082
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Superhydrophobic polysulfone (PSU)/carbon nanotubes (CNTs) nanocomposite coating with biomimetic golden spherical cactus surface structure (with micro-sphere and nano-thorns) was fabricated by electrostatic powder-spraying method. The superhydrophobic PSU-CNTs-FEP nanocomposite (PCFn) coating can be applied to different substrates such as aluminum plate, steel plate, glass plate, and steel pipe, which exhibited a maximum water contact angle all beyond 164 +/- 1.5 degrees and low slide angle of less than 5 +/- 0.5 degrees. The morphology, chemical composition and spherical cactus structure formation of the coatings were investigated. The electrostatic spraying and micro-phase separation promise a synergistic effect on promoting the superhydrophobicity, self-cleaning and high durability of PCFn coating. Moreover, the PCFn coating demonstrated unique multiple anti-corrosion effects, providing with air bubble corrosion protection, physical shielding and decreasing interfacial electronic agglomeration effect, which promises the wide applicability of the PCFn coatings in different engineering processes.
引用
收藏
页码:670 / 679
页数:10
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