Verification of the nucleation theorem for the internally constrained one-dimensional hard rod fluid

被引：1

作者：

Punnathanam, S ^{[1
]}

Corti, DS ^{[1
]}

机构：

[1] Purdue Univ, Sch Chem Engn, W Lafayette, IN 47907 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2002年 / 117卷 / 13期

关键词：

Cavity resonators - Liquids - Particle size analysis - Statistical mechanics - Thermodynamic properties;

D O I：

10.1063/1.1503334

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The generalized nucleation theorem as derived by Bowles [J. Chem. Phys. 115, 1853 (2001)] had been verified for nonuniformities generated by a cavity and a cluster within the one-dimensional hard rod fluid. We further verify the nucleation theorem for nonuniformities created by a cavity and by a cluster containing m particles within the internally constrained hard rod fluid. The given results provide additional evidence of the validity of the generalized nucleation theorem even down to the molecular level. (C) 2002 American Institute of Physics.

引用

页码：6169 / 6175

页数：7